Answers
When an unsymmetrical alkene such as propene is treated with N-bromosuccinimide in aqueous dimethyl sulfoxide, the major product has the bromine atom bonded to the less highly substituted carbon atom. This reaction describes a non-Markovnikov orientation.
In the reaction between an unsymmetrical alkene (such as propene) and N-bromosuccinimide (NBS) in the presence of aqueous dimethyl sulfoxide (DMSO), the major product is formed with the bromine atom bonded to the less highly substituted carbon atom of the alkene.
In Markovnikov's addition, the major product is formed by adding the electrophile (in this case, the bromine atom) to the carbon atom with more hydrogen atoms bonded to it. However, the given reaction exhibits non-Markovnikov selectivity, as the bromine atom adds to the less substituted carbon atom.
This non-Markovnikov selectivity can be attributed to the presence of DMSO, which acts as a polar solvent and helps generate a bromine radical (Br•). The radical intermediate can then undergo reaction with the alkene, leading to the observed regioselectivity where the bromine atom adds to the less substituted carbon. This process is known as a radical addition reaction.
Hence, the reaction demonstrates a non-Markovnikov orientation due to the addition of the bromine atom to the less highly substituted carbon atom of the propene molecule.
Learn more about the Markovnikov rule here:
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Related Questions
Catalysts are substances that increase the rate of reaction but can be recovered unchanged at the end of the reaction. Catalysts can be classified as either homogeneous (same state as reactants) or heterogeneous (different state than reactants).
Platinum is used to catalyze the hydrogenation of ethylene:
H2(g)+CH2CH2(g)−⟶Pt(s)CH3CH3(g)
Chlorofluorocarbons (CFCs) catalyze the conversion of ozone (O3) to oxygen gas (O2):
2O3(g)−⟶CFC(g)3O2(g)
Magnesium catalyzes the disproportionation of hydrogen peroxide to produce water and oxygen:
2H2O2(aq)−⟶Mg(s)2H2O(l)+O2(g)
What type of catalysts are platinum, CFCs, and magnesium under these conditions?
Answers
Answer:
- Platinum acts as a heterogeneous catalyst in the hydrogenation of ethylene.
- CFCs act as homogeneous catalysts in the conversion of ozone to oxygen gas.
- Magnesium acts as a heterogeneous catalyst in the disproportionantion of hydrogen peroxide.
Explanation:
Hello,
For the given reactions, considering the definition of homogeneous and heterogeneous catalyst, we can identify that is each catalyst behave as follows:
- Platinum acts as a heterogeneous catalyst in the hydrogenation of ethylene as all the reactants are gaseous but it remains solid.
- CFCs act as homogeneous catalysts in the conversion of ozone to oxygen gas as it remains gaseous as well as both ozone and oxygen.
- Magnesium acts as a heterogeneous catalyst in the disproportionantion of hydrogen peroxide as it is solid whereas the other species are aqueous, liquid and gaseous
Best regards.
which statements describe how chemical formulas, such as H2O, represent compounds?
Answers
Answer:
2 Hydrogen One oxygen
Explanation:
One of the radioactive isotopes used in chemical and medical research is sulfur-35, which has a half-life of 87 days. How long would it take for 0.25 g to remain of a 1.00 g sample of sulfur-35
Answers
Answer:
Time taken = 174 days
Explanation:
Half life is the time take for a subsrtance taken to decay to half of it's origial or initial concentration.
In this probel, the haf life is 87 days, this means that after evry 87 days, the concentration or mass of sulfur-35 decreases by half.
If the starting mass is 1.00g, then we have;
1.00g --> 0.5g (First Half life)
0.5g --> 0.25g (Second half life)
This means that sulphur-335 would undergo two half lives for 0.25g to remain.
Total time taken = Number of half lives * Half life
Time taken = 2 * 87
Time taken = 174 days
A gaseous system undergoes a change in temperature and volume. What is the entropy change for a particle in this system if the final number of microstates is 0.842 times that of the initial number of microstates
Answers
Answer: -2.373 x 10^-24J/K(particles
Explanation: Entropy is defined as the degree of randomness of a system which is a function of the state of a system and depends on the number of the random microstates present.
The entropy change for a particle in a system depends on the initial and final states of a system and is given by Boltzmann equation as
S = k ln(W) .
where S =Entropy
K IS Boltzmann constant ==1.38 x 10 ^-23J/K
W is the number of microstates available to the system.
The change in entropy is given as
S2 -S1 = kln W2 - klnW1
dS = k ln (W2/W1)
where w1 and w2 are initial and final microstates
from the question, W2(final) = 0.842 x W1(initial), so:
= 1.38*10-23 ln (0.842)
=1.38*10-23 x -0.1719
= -2.373 x 10^-24J/K(particles)
Problem PageQuestion Liquid hexane CH3CH24CH3 will react with gaseous oxygen O2 to produce gaseous carbon dioxide CO2 and gaseous water H2O. Suppose 60. g of hexane is mixed with 74.5 g of oxygen. Calculate the maximum mass of water that could be produced by the chemical reaction. Round your answer to 3 significant digits.
Answers
Answer:
43.45g of water would be produced from the reaction.
Explanation:
Liquid became reacts with oxygen to produce carbon dioxide and water.
This type of reaction is known as combustion reaction between alkanes.
Equation of reaction.
Assuming the reaction occurs in an unlimited supply of oxygen,
2C₆H₁₄ + 19O₂ → 12CO₂ + 14H₂O
From the above equation of reaction,
2 moles of C₆H₁₄ reacts with 19 moles of O₂ to produce 14 moles of H₂O.
To find the theoretical mass,
Number of moles = mass / molar mass
Molar mass of C₆H₁₄ = 86g/mol
Molar mass of O₂ = 16g/mol × 2 = 32g/mol
Molar mass of H₂O = 18g/mol
Mass of H₂O = number of moles × molar mass
Mass of H₂O = 14 × 18 = 252g
Mass of C₆H₁₄ = number of moles × molar mass
Mass of C₆H₁₄ = 2 × 86 = 172g
Mass of O₂ = number of moles × molar mass
Mass of O₂ = 19 × 32 = 608g
From the equation of reaction,
172g of C₆H₁₄ reacts with 608g of O₂ to produce 252g of H₂O
(172 + 608)g of reactants produce 252g of H₂O
780g of reactants produce 252g of H₂O
(60 + 75.5)g of reactants will produce a x g of H₂O
780g of reactants = 252g of H₂O
134.5g of reactants = x g of H₂O
X = (134.5 × 252) / 780
X = 43.45g of H₂O
Therefore, 43.45g of H₂O would be produced from 60g of hexane and 74.5g of oxygen
Answer:
[tex]m_{H_2O}=30.9gH_2O[/tex]
Explanation:
Hello,
In this case, the combustion of hexane is given by:
[tex]C_6H_{14}+\frac{19}{2} O_2\rightarrow 6CO_2+7H_2O[/tex]
The next step is to compute the reacting moles of hexane:
[tex]n_{C_6H_{14}}=60gC_6H_{14}*\frac{1molC_6H_{14}}{86gC_6H_{14}} =0.698molC_6H_{14}[/tex]
Then, the moles of hexane consumed by 74.5 g of oxygen using the molar ratio in the chemical reaction (1:19/2):
[tex]n_{C_6H_{14}}=74.5gO_2*\frac{1molO_2}{32gO_2} *\frac{1molC_6H_{14}}{19/2molO_2} =0.245molC_6H_{14}[/tex]
Therefore, as less moles of hexane are consumed by oxygen, it is in excess, so we compute the mass of water produced by the consumed 0.245 moles of hexane:
[tex]m_{H_2O}=0.245molC_6H_{14}*\frac{7molH_2O}{1molC_6H_{14}}*\frac{18gH_2O}{1molH_2O} \\\\m_{H_2O}=30.9gH_2O[/tex]
Best regards.
Calculate the percent saturated fat in the total fat in butter
Answers
The decomposition of hydrogen peroxide, H2O2, has been used to provide thrust in the control jets of various space vehicles. Determine how much heat (in kJ) is produced by the decomposition of 1.71 mol of H2O2 under standard conditions.
Answers
Answer:
[tex]Q=-361.56kJ[/tex]
Explanation:
Hello,
In this case, the decomposition of hydrogen peroxide is given by:
[tex]2H_2O_2\rightarrow 2H_2O+O_2[/tex]
Which occurs in gaseous phase, therefore the enthalpy of reaction is:
[tex]\Delta _rH=2\Delta _fH_{H_2O}-2\Delta _fH_{H_2O_2}[/tex]
Oxygen is not included as it is a pure element. The enthalpies of formation for both hydrogen peroxide and water are -136.11 and -241.83 kJ/mol respectively, so we compute the enthalpy of reaction:
[tex]\Delta _rH=2(-241.83kJ/mol)-2(-136.11kJ/mol)=-211.44kJ/mol[/tex]
Then, the total heat that is released for 1.71 mol of hydrogen peroxide is:
[tex]Q=n*\Delta _rH=1.71mol*-211.44kJ/mol\\\\Q=-361.56kJ[/tex]
Whose sign means a released heat.
Regards.
Why is tape attracted to my skin? Give explanation
Answers
Answer:
Since the tape has extra electrons, it has a negative charge. When you move your finger close to the tape, electrons in your skin are repelled and move away. This makes the skin on your finger tip have a slight positive charge. Since positive and negative attract, the tape moves toward your finger.
Ethanol, , boils at 78.29 °C. How much energy, in joules, is required to raise the temperature of 2.00 kg of ethanol from 26.0 °C to the boiling point and then to change the liquid to vapor at that temperature? (The specific heat capacity of liquid ethanol is 2.44 J/g ∙ K, and its enthalpy of vaporization is 855 J/g.)
Answers
Answer:
THE HEAT REQUIRED TO CHANGE 2 KG OF ETHANOL FROM 26 °C TO THE BOILING POINT AND TO VAPOR AT THAT TEMPERATURE IS 1965.175 KJ.
Explanation:
Boiling point of ethanol = 78.29 °C = 78.29 + 273 K = 351.29 K
Mass = 2 kg = 2000 g
Final temp. = 26.0 °C = 26 + 273 K= 299 K
Change in temperature = (78.29 - 26) °C = 52.29 °C
1. Heat required to raise the temperature from 26 °C to the boiling point?
Heat = mass * specific heat * change in temperature
Heat = 2000 * 2.44 * 52.29
Heat = 255 175.2 J
2. Heat required to change the liquid to vapor at that temperature?
Heat = mass * enthalphy of vaporization
Heat = 2000 * 855
Heat =1 710000 J
The total heat required to raise the temperature of 2 kg of ethanol from 26 °C to the boiling point and then to change the liquid to vapor at that temperature will be:
Heat = mcT + m Lv
Heat = 255 175.2 J + 1710000 J
Heat = 1965175.2 J
Heat = 1965.175 kJ of heat.
What is the probability that an offspring will have a
heterozygous genotype? |
Answers
Answer:
25,50,25
Explanation:
3. Crystalline structural unit of barium metal is a body-centered cubic cell. The edge length of the unit cell is 5.02x10-8 cm. The density of the metal is 5.30 g/cm3. Assume that 68% of the unit cell is occupied by Ba atoms. The molar mass of barium is 137.3 g/mol. Using this information, calculate Avogadro’s number. Show your calculation procedure that allows you to derive Avogadro’s number. Your answer must show six digits after the decimal point (i.e., 6.pppx1023) that is not necessarily the same as the known value. By showing your calculation-result down to six digits after the decimal point, you showcase that you did calculate the number, instead of simply adopting the known Avogadro’s number available in open resources.
Answers
Answer:
The Avogadro's number is [tex]N_A = 6.02289 *10^{23}[/tex]
Explanation:
From the question we are told that
The edge length is [tex]L = 5.02 * 10^{-8} \ cm= \frac{5.02 * 10^{-8} }{100} = 5.02 * 10^{-10}[/tex]
The density of the metal is [tex]\rho = 5.30\ g/cm^3 = 5.30 * \frac{g}{cm^3} * \frac{1*10^6}{1*10^3} = 5.30 *10^3kg/m^3[/tex]
The molar mass of Ba is [tex]Z = 137.3 \ g/mol = \frac{137.3}{1000} = 0.1373 \ kg / mol[/tex]
Generally the volume of a unit cell is
[tex]V = L^3[/tex]
substituting value
[tex]V = [5.02 *10^{-10}]^3[/tex]
[tex]V = 1.265*10^{-28}\ m^3[/tex]
From the question we are told that 68% of the unit cell is occupied by Ba atoms and that the structure is a metal which implies that the crystalline structure will be (BCC),
The volume of barium atom is
[tex]V_a = \frac{V}{2} * 0.68[/tex]
substituting value
[tex]V_a = \frac{ 1.265*10^{-28}}{2} * 0.68[/tex]
[tex]V_a = 4.301 *10^{-29} \ m^3[/tex]
The Molar mass of barium is mathematically represented as
[tex]Z = N_A V_a * \rho[/tex]
Where [tex]N_A[/tex] is the Avogadro's number
So
[tex]N_A = \frac{ Z}{ V_a * \rho}[/tex]
substituting value
[tex]N_A = \frac{ 0.1373}{ 4.301*10^{-29} * 5.3*10^{3}}[/tex]
[tex]N_A = 6.02289 *10^{23}[/tex]
At that volume is measured to be 755 mm of Hg. If the lungs are compressed to a newA healthy male adult has a lung capacity around 6.00 liters. The pressure in the lungs volume of 3.81 liters, what would be the new pressure in the lungs? What would happen to the air in the lungs?
Answers
Answer:
1188.976 mmHg
Explanation:
Initial pressure P1= 755 mmHg
Initial volume V1 = 6.00 litres
Final volume V2 = 3.81 litres
Final pressure P2= the unknown
Now applying Boyle's Law,we have;
P1V1 = P2V2
Since P2 is the unknown then it has to be made the subject of the formula.
P2=P1V1/ V2
P2= 755 × 6.00/ 3.81
P2= 1188.976 mmHg
Therefore, the new pressure is; 1188.976 mmHg
Consider the following reaction:
2NO(g)+O2(g)→2NO2(g)
Estimate ΔG∘ for this reaction at each of the following temperatures and predict whether or not the reaction will be spontaneous. (Assume that ΔH∘ and ΔS∘ do not change too much within the give temperature range.) I need to find the temperature are 298K and 702K. For 298K It is simple because at standard temperature
ΔG∘ = DG(products)- DG(reactants).
Answers
Answer:
A. [tex]\mathbf{\Delta G^0 = -72.6 \ kJ/mol}[/tex] ; as such the reaction is said to be spontaneous since the value of [tex]\mathbf{\Delta G^0 }[/tex] is negative.
B. [tex]\mathbf{\Delta G^0_{702 \ K} = -13.29 \ kJ/mol.K}}[/tex] and the reaction is spontaneous
Explanation:
The equation for this chemical reaction is :
[tex]2NO_{(g)} +O_{2(g)} \to 2NO_{2(g)}[/tex]
Using the following relation to calculate [tex]\Delta G^0[/tex];
[tex]\Delta G^0 = [2(\Delta G^0_{NO_{2(g)}}] - [1(\Delta G^0_{O_{2(g)}})+ 2(\Delta G^0_{NO_{g}})][/tex]
At 298 K; the standard Gibbs Free Energy for the formation are as follows:
[tex]\Delta G^0_{NO_{2(g)}} = 51.2 \ kJ/mol[/tex]
[tex]\Delta G^0_{O_{2(g)}} = 0[/tex]
[tex]\Delta G^0_{NO_{g}}= 87.6 \ kJ/mol[/tex]
Replacing them into the above equation;
[tex]\Delta G^0 = [2(51.2 \ kJ/mol}] - [1(0)+ 2(87.6 \ kJ/mol})][/tex]
[tex]\Delta G^0 = [102.4 \ kJ/mol}] - [175.2 \ kJ/mol})][/tex]
[tex]\mathbf{\Delta G^0 = -72.6 \ kJ/mol}[/tex]
Thus; [tex]\mathbf{\Delta G^0 = -72.6 \ kJ/mol}[/tex] ; as such the reaction is said to be spontaneous since the value of [tex]\mathbf{\Delta G^0 }[/tex] is negative.
B.
Using the same above chemical equation;
The relation used for calculating [tex]\mathbf{\Delta G^0}[/tex] of the reaction when the temperature is 702 K is:
[tex]\Delta G^0_{702 \ K} = \Delta H^0_{xn} - T \Delta S^0_{rxn}[/tex]
where;
[tex]\Delta G^0_{702 \ K} =[/tex] Gibbs free energy of the reaction at 702 K
[tex]\Delta H^0_{xn}[/tex] = standard enthalpy of the reaction = -116.2 kJ/mol
[tex]\Delta S^0_{rxn}[/tex] = standard entropy of the reaction = -146.6 J/mol/K
Temperature T = 702 K
[tex]\Delta G^0_{702 \ K} = -1162. \ kJ/mol - 702 \ K ( -146.6 \ J/mol. K (\dfrac{1 \ kJ }{1000 \ J})[/tex]
[tex]\Delta G^0_{702 \ K} = -1162. \ kJ/mol - 702 \ K ( 0.1466 \ kJ/mol.K})[/tex]
[tex]\Delta G^0_{702 \ K} = -13.2868 \ kJ/mol.K}[/tex]
[tex]\mathbf{\Delta G^0_{702 \ K} = -13.29 \ kJ/mol.K}}[/tex]
Thus [tex]\mathbf{\Delta G^0_{702 \ K} = -13.29 \ kJ/mol.K}}[/tex] and the reaction is spontaneous
When 1.550 gg of liquid hexane (C6H14)(C6H14) undergoes combustion in a bomb calorimeter, the temperature rises from 25.87 ∘C∘C to 38.13 ∘C∘C. Find ΔErxnΔErxn for the reaction in kJ/molkJ/mol hexane. The heat capacity of the bomb calorimeter, determined in a separate experiment, is 5.73 kJ/∘CkJ/∘C.
Answers
Answer:
ΔErxn[tex]= -3.90*10^3KJ[/tex]
Explanation:
Given from the question
T1 = 25.87∘C
T2= 38.13∘C.
C= 5.73Kj/C
CHECK THE ATTACHMENT FOR DETAILED EXPLATION
Which of the following is named using the unmodified element name and adding the word "ion"? Select the correct answer below:
a. simple cations (monatomic cations of elements of only one possible charge)
b. simple anions (monatomic anions of elements of only one possible charge)
c. simple protons
d. simple neutrons
Answers
Answer:
simple cations (monatomic cations of elements of only one possible charge)
Explanation:
Simple cations (monatomic cations of elements of only one possible charge) are named using the unmodified element name and adding the word "ion"
For example, the Na+ is named the sodium ion.
An atom or molecule with a net electric charge as a result of the loss or gain of one or more electrons is known as an ion.
iron oxide + oxygen equals to ?
Answers
Answer:
It's ferric oxide Fe2O3
Explanation:
I don't say u must have to mark my ans as brainliest but if it has really helped u plz don't forget to thank me plz...
1.Draw the born-Haber lattice energy cycle for sodium chloride. Explain the concept of resonance using the nitrate ion structure.
Answers
Answer:
1. Born Haber cycle is used to calculate enthalpy of formation of an ionic solid
2. Resonance structures are used to represent the bonding in some chemical species.
Explanation:
The Born–Haber cycle is a method popularly known in chemistry used in computing enthalpy. The enthalpy of formation of an ionic solid cannot be measured directly. The lattice enthalpy refers to the enthalpy change involved in the formation of an ionic compound from gaseous ions the process is exothermic process. A Born–Haber cycle works on the principle of Hess's law. It can be used to calculate the lattice enthalpy by comparing the standard enthalpy change of formation of the ionic compound from the elements to the enthalpy required to make gaseous ions from the elements.
Resonance is an idea introduced by Linus Pauling to explain chemical bonding from the valence bond perspective. The idea of resonance affords us the opportunity to describe the bonding in certain molecules by combining several structures called chemical or canonical structures. The real structure of the specie lie somewhere between the structures indicated by the resonance structures. The resonance structures of the nitrate ion are shown in the image attached.
Methods in electrochemistry that can be used for the separation of proteins and enzymes?
Answers
Answer:
Some of the methods in Methods in electrochemistry that can be used for the separation of proteins and enzymes are as follows:
Redox transformations: In this method enzymes or proteins would be adsorbed on the electrode surface and facilitates direct electron transfer that causes denaturation and loss of their electrochemical activities and bioactivities. It is widely used in biosensors and biofuel cells.
Protein electrophoresis: In this process proteins are seperated by placing them in a gel matrix in the presence of an electrical field. In this method a negative charge is applied so that proteins move towards a positive charge.
A chemistry student is given 600. mL of a clear aqueous solution at 37° C. He is told an unknown amount of a certain compound X is dissolved in the solution. The student allows the solution to cool to 21° C. At that point, the student sees that a precipitate has formed. He pours off the remaining liquid solution, throws away the precipitate, and evaporates the water from the remaining liquid solution under vacuum. More precipitate forms. The student washes, dries and weighs the additional precipitate. It weighs 0.084 kg. Using only the information from above, can you calculate the solubility of X at 21° C?If yes, calculate it. Be sure your answer has a unit symbol and the right number of significant figures.
Answers
Answer:
The solubility is [tex]S = 0.0014 \ g[/tex]
Explanation:
From the question we are told that
The volume of the solution is [tex]V = 600 mL[/tex]
The initial temperature is [tex]T_i = 37 ^oC[/tex]
The final temperature is [tex]T_f = 21^oC[/tex]
The additional precipitate is [tex]m = 0.084 \ kg = 84 \ g[/tex]
Yes because the solubility of the substance X is the amount of X needed to saturate a unit volume of the solvent (for solubility of a solute to be calculated the solute must be able to saturate the solvent)
now we see that the substance X saturated the solvent because a precipitate was formed which the student threw away
The solubility at 21 ° C is mathematically represented as
[tex]S = \frac{m}{m_w * 100 g \ of water }[/tex]
Mass of water([tex]m_w[/tex]) in the solution is mathematically represented as
[tex]m_w = V * \rho_w[/tex]
Where [tex]\rho = 1 \frac{g}{mL}[/tex]
So
[tex]m_w =600 * 1[/tex]
[tex]m_w =600g[/tex]
So
[tex]S = \frac{84}{600 * 100 g \ of water }[/tex]
[tex]S = 0.0014 \ g[/tex]
Aqueous hydrobromic acid reacts with solid sodium hydroxide to produce aqueous sodium bromide and liquid water . If of sodium bromide is produced from the reaction of of hydrobromic acid and of sodium hydroxide, calculate the percent yield of sodium bromide.
Answers
Answer:
The percentage yield is 50%
Give two examples (i.e. list 2 elements that are examples) of: a. an atom with a half-filled subshell b. an atom with a completely filled outer shell c. an atom with its outer electrons occupying a half-filled subshell and a filled subshell
Answers
Answer:
an atom with a half-filled subshell - hydrogen
an atom with a completely filled outer shell - argon
an atom with its outer electrons occupying a half-filled subshell and a filled subshell- copper
Explanation:
The outermost shell or the valence shell of the atom is the last shell in the atom. Chemical reactions occur at this outer most shell. The number of electrons on the outermost shell of an atom determines the group to which it belongs in the periodic table as well as its chemical properties.
Hydrogen has a half filled 1s sublevel. Only one electron is present in this sublevel.
Let us consider argon
1s2 2s2 2p6 3s2 3p6
The outermost ns and np levels are completely filled. Thus the outermost shell is completely filled.
In the last case; let us look at the electronic configuration of nitrogen;
1s2 2s2 2p3
The outermost 2p subshell is exactly half filled while the 2s sublevel is fully filled. The outermost shell of nitrogen is made up of 2s2 and 2p3 sublevels.
Which of these scientists diagnosed smallpox and measles?
A. Nicolaus Copernicus
B. Al-Razi
C. Archimedes
D. Rosalind Franklin
Answers
Answer:
B
Explanation:
Consider the following system at equilibrium: P(aq)+Q(aq)⇌3R(aq) Classify each of the following actions by whether it causes a leftward shift, a rightward shift, or no shift in the direction of the net reaction. Drag the appropriate items to their respective bins.
Items:1) Increase [P]2) Increase [Q]3) Increase [R]4) Decrease [P]5) Decrease [Q]6) Decrease [R]7) Triple [P] and reduce [Q] to one third8) Triple both [Q] and [R]
Answers
Explanation:
P(aq)+Q(aq)⇌3R(aq)
This problem involves applying LeChatelier's principle.
LeChatelier's principle states that whenever a system in equilibrium is disturbed, the equilibrium position would change in order to annul that change.
1) Increase [P]
This would cause the equilibrium position to shift to the right. This is because more reactions have been added, to annul that change more products have to be formed.
2) Increase [Q]
This would cause the equilibrium position to shift to the right. This is because more reactions have been added, to annul that change more products have to be formed.
3) Increase [R]
This would cause the equlibrium position to shift to the left. This is because more products have been formed, to annul that change more reactants have to be formed.
4) Decrease [P]
This would cause the equlibrium position to shift to the left. This is because there are now less reactants, to annul that change more reactants have to be formed.
5) Decrease [Q]
This would cause the equilibrium position to shift to the left. This is because there are now less reactants, to annul that change more reactants have to be formed.
6) Decrease [R]
This would cause the equilibrium position to shift to the right. This is because there are now less products, to annul that change more products have to be formed.
7) Triple [P] and reduce [Q] to one third
No shift in the direction of the net reaction because both changes cancels each other.
8) Triple both [Q] and [R]
No shift in the direction of the net reaction because both changes cancels each other.
For some hypothetical metal the equilibrium number of vacancies at 750°C is 2.8 × 1024 m−3. If the density and atomic weight of this metal are 5.60 g/cm3 and 65.6 g/mol, respectively, calculate the fraction of vacancies for this metal at 750°C.
Answers
Answer:
The correct answer is 5.447 × 10⁻⁵ vacancies per atom.
Explanation:
Based on the given question, the at 750 degree C the number of vacancies or Nv is 2.8 × 10²⁴ m⁻³. The density of the metal is 5.60 g/cm³ or 5.60 × 10⁶ g/m³. The atomic weight of the metal given is 65.6 gram per mole. In order to determine the fraction of vacancies, the formula to be used is,
Fv = Nv/N------ (i)
Here Nv is the number of vacancies and N is the number of atomic sites per unit volume. To find N, the formula to be used is,
N = NA×P/A, here NA is the Avogadro's number, which is equivalent to 6.022 × 10²³ atoms per mol, P is the density and A is the atomic weight. Now putting the values we get,
N = 6.022 × 10²³ atoms/mol × 5.60 × 10⁶ g/m³ / 65.6 g/mol
N = 5.14073 × 10²⁸ atoms/m³
Now putting the values of Nv and N in the equation (i) we get,
Fv = 2.8 × 10²⁴ m⁻³ / 5.14073 × 10²⁸ atoms/m^3
Fv = 5.44669 × 10⁻⁵ vacancies per atom or 5.447 × 10⁻⁵ vacancies/atom.
Based on this information what is the most likely reason for refrigerating most foods reduce the rate at which they spoil
Answers
Answer: The lower temperature reduces molecule speeds, reducing the number of effective collisions.
Explanation:
WILL GIVE BRAINLIEST!!!!! will give brainliest!!!!! ---------Write the molecular equation, complete ionic equation and net ionic equation of Barium nitrate reacting with potassium carbonate.
Answers
Answer:
Molecular:
Ba(NO3)2 + K2CO3 -> BaCO3 + 2KNO3
Complete ionic:
Ba2+ + 2NO3- + 2K+ + CO3 2- -> BaCO3 + 2K+ + 2NO3-
Net ionic:
Ba2+ + CO3 2- - > BaCO3
Explanation:
Molecular consists of all species reacting.
Complete ionic consists of all ionic species (ex. K+, NO3-) separated, as well as any compounds that didn't dissociate into ions (BaCO3 doesn't dissolve).
Net ionic doesn't include spectator ions (in this case, nitrate and potassium) and only species that aren't present on both sides of the arrow (barium and carbonate become a solid precipitate, so the ions aren't present as products, making them appear in the net ionic equation).
At 25 oC, the rate constant for the first-order decomposition of a pesticide solution is 6.40 x 10-3 min-1. If the starting concentration of pesticide is 0.0314 M, what concentration will remain after 62.0 minutes at 25 oC? 3.12 x 10-2 M 47.4 M 2.11 x 10-2 M 4.67 x 10-2 M 8.72 M
Answers
Answer:
[tex]2.11\ * 10^{-2}[/tex] is the correct answer to the given question.
Explanation:
Given k=6.40 x 10-3 min-1.
According to the first order reaction .
The concentration of time can be written as
[tex][\ A\ ]\ = \ [\ A_{0}\ ] * e \ ^\ {-kt}[/tex]
Here [tex][\ A\ ]_{0}[/tex] = Initial concentration.
So [tex][\ A\ ]_{0}= 0.0314 M[/tex]
Putting this value into the above equation.
[tex]0.0314 \ *\ e^{6.40 x 10^{-3} \ * \ 62.0 }[/tex]
=0.211 M
This can be written as
[tex]=\ 2.11 *\ 10^{-2}[/tex]
A new non-electrolyte molecule is discovered. When 241 mg of the molecule is dissolved in 250.0 mL of water, it has an osmotic pressure of 0.072 atm at 25 oC.What is the molar mass of the molecule
Answers
Answer:
327.89g/mol
Explanation:
Step 1:
The following data were obtained from the question:
Van 't Hoff factor (i) = 1 (since the molecule is non-electrolyte)
Temperature (T) = 25°C = 25°C + 273 = 298K
Gas constant (R) = 0.0821 atm.L/Kmol
Mass of molecule = 241mg
Volume of water = 250mL
Molarity (M) =?
Osmotic pressure (Π) = 0.072 atm
Step 2:
Determination of the molarity of the molecule.
This can be obtained as follow:
Π = iMRT
0.072 = 1 x M x 0.0821 x 298
Divide both side by 0.0821 x 298
M = 0.072 / (0.0821 x 298)
M = 2.94×10¯³ mol/L
Step 3:
Determination of the number of mole of the molecule. This can be obtained as follow:
Molarity = 2.94×10¯³ mol/L
Volume of water = 250mL = 250/1000 = 0.25L
Mole of molecule =..?
Molarity = mole /Volume
2.94×10¯³ = mole / 0.25
Cross multiply
Mole of molecule = 2.94×10¯³ x 0.25
Mole of molecule = 7.35×10¯⁴ mole.
Step 4:
Determination of the molar mass of the molecule.
Mole of molecule = 7.35×10¯⁴ mole.
Mass of molecule = 241mg = 241×10¯³g
Molar mass of molecule =..?
Mole = Mass /Molar Mass
7.35×10¯⁴ = 241×10¯³/ Molar Mass
Cross multiply
7.35×10¯⁴ x molar mass = 241×10¯³
Divide both side by 7.35×10¯⁴
Molar Mass = 241×10¯³/7.35×10¯⁴
Molar Mass = 327.89g/mol
Therefore, the molar mass of the molecule is 327.89g/mol
what is the equation for "acid dissociation constant" of "carbonic acid"
Answers
Answer:
H2CO3 = 2H+ + CO3-
Explanation:
It is simply what carbonic acid breaks down into when placed in water. Since carbonic acid is made up of H and CO3, these are the products.
(a) Titration curve for the titration of 5.00 mL 0.010 M NaOH(aq) with 0.005 M HCl(aq), indicating the pH of the initial and final solutions and the pH at the stoichiometric point.
What volume of HCl has been added at
(b) the stoichiometric point
(c) the halfway point of the titration?
Answers
Answer:
AT STOICHIOMETRIC POINT, THE VOLUME OF ACID ADDED IS 0.01 L
AT HALF-WAY POINT, THE VOLUME OF ACID IS 0.0050 L
Explanation:
In solving titration problems, you must remember this formula;
MaVa = MbVb
Since M a= 0.005 M
Mb = 0.010 M
Vb = 5 mL = 5 /1000 = 0.005 L
Va = unknown.
Solving for Va, we have:
Va = MbVb / Ma
Va = 0.010 * 0.005 / 0.005
Va = 0.01 L
So therefore, the volume of acid added at:
1. the stoichiometric point is 0.01 L
2. half-way point of titration is 0.01 /2 = 0.0050 L
For the pH:
Since HCl is a strong acid, it dissociate into {H30}+ ion.
First calculate the number of moles of hydronium ion
number of mole = concentration of hydronium ion {H30}+ * Volume
n = 0.005 * 0.01 = 0.00005 moles
A. At initial point of the titration, the volume of base added is 0 L
{H30]+ = n(H+)/ V = 0.00005 / 0.01 = 0.005 M
pH = - log {0.005}
pH = 2.3
B. At the final point, since the volumes and concentrations of acid and base are the same, the pH is equal to 7.
n(H+) = n(OH^-)
pH = 7
