Imagine a piston with an external pressure of 1 bar that contains liquid water, water vapor, and nitrogen gas. the piston is in thermal contact with a large reservoir held at 270.15 k. initially the partial pressure of water vapor in the piston is 489 pa; nothing changes for a long time. at some point the water crystallizes and the system comes to a new equilibrium; the new partial pressure of water vapor in the piston is 475 pa. calculate the difference in the chemical potential for liquid and crystalline water at 270.15 k. (to think about: does the sign of your answer make sense

Answers

Answer 1

The difference in the chemical potential for liquid and crystalline water at 270.15 K is -0.97 J/mol.


1. Convert given pressures to atm: initial partial pressure of water vapor (P1) = 489 Pa / 101325 Pa/atm = 0.00482 atm, and new partial pressure (P2) = 475 Pa / 101325 Pa/atm = 0.00469 atm.


2. Use the Clausius-Clapeyron equation: ln(P2/P1) = -(ΔH_sub/R)(1/T2 - 1/T1), where ΔH_sub is the enthalpy of sublimation, R is the gas constant, and T1 and T2 are the initial and final temperatures, both equal to 270.15 K.


3. Rearrange the equation to solve for ΔH_sub: ΔH_sub = R * (ln(P2/P1))/(1/T2 - 1/T1), and substitute the values: ΔH_sub = 8.314 J/mol K * (ln(0.00469/0.00482))/(0 - 0) = -0.97 J/mol.


4. The negative sign makes sense as the system moves to a new equilibrium with a lower chemical potential for crystalline water, indicating a more stable phase.

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Related Questions

A0.205g sample of caco3(mr=100.1g/mol) is added to a flask a long with7.50 mlof2.00mhcl. caco3(aq)+2hcl(aq)→ cacl2(aq)+h2o(l)+co2(g) enough water is then added to make a 125.0ml solution. a10.00ml aliquot of this solution is taken and titrated with 0.058m naoh. naoh(aq)+hcl(aq)→ h2o(l)+nacl(aq) how many ml of naoh are used?​

Answers

129.3 mL of NaOH are required to react with all the HCl in the 10.00 mL aliquot.

To solve this problem, we need to use stoichiometry and the concept of limiting reagents.

First, let's calculate the number of moles of HCl used in the reaction:
7.50 mL of 2.00 M HCl = 0.015 mol HCl

Next, let's use stoichiometry to determine the number of moles of CaCO₃ that reacted with the HCl:
1 mol CaCO₃ reacts with 2 mol HCl
0.015 mol HCl x (1 mol CaCO₃ / 2 mol HCl) = 0.0075 mol CaCO₃

Now we can use the mass and molar mass of CaCO₃ to determine the mass of CaCO₃ used:
mass CaCO₃ = number of moles x molar mass
mass CaCO₃ = 0.0075 mol x 100.1 g/mol = 0.751 g

However, this mass was used to make a 125.0 mL solution, so we need to calculate the concentration (in M) of this solution:
0.751 g / 125.0 mL = 0.006008 M

Now we can use the volume and concentration of the NaOH solution to determine the number of moles of NaOH used:
10.00 mL of 0.058 M NaOH = 0.00058 mol NaOH

Finally, we can use stoichiometry to determine the volume of NaOH required to react with all the HCl in the 10.00 mL aliquot:
1 mol HCl reacts with 1 mol NaOH
0.0075 mol HCl x (1 mol NaOH / 1 mol HCl) = 0.0075 mol NaOH
volume of NaOH = number of moles / concentration
volume of NaOH = 0.0075 mol / 0.058 M = 0.1293 L = 129.3 mL

Therefore, 129.3 mL of NaOH are required to react with all the HCl in the 10.00 mL aliquot.

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A sample of river water taken near to a factory
shows a pH of 5.
al Do you think this represents a pollution
problem? Give reasons for your answer.
b What other evidence might you need to
consider before reaching a conclusion?

Answers

a) A pH of 5 for river water near a factory does suggest a potential pollution problem. The normal pH range for most natural waters is around 6.5-8.5. pH values below 6.5 can indicate acidification, which can be caused by pollutants such as sulfur dioxide and nitrogen oxides from industrial activities, or from natural sources such as acid rain.

What is the river water about?

A pH of 5 is more acidic than most natural waters and could indicate the presence of acidic pollutants in the water.

Therefore, in terms of b) Other evidence that would be useful to consider before reaching a conclusion about whether the pH of 5 represents a pollution problem includes:

Information about the specific factory located near the river and the activities that take place there. This could help to identify any potential sources of pollutants that could be causing the decrease in pH.Water quality testing for other parameters such as dissolved oxygen, temperature, and nutrient levels. This could help to identify other potential sources of pollution, and could help to determine the overall health of the river ecosystem.A comparison of the pH of the river water at different times of year, and at different locations along the river. This could help to identify any seasonal or regional patterns in the pH levels, which could be related to natural factors such as rainfall or the geology of the area.

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Suppose you are a farmer trying to produce a high yield of corn to sell for the
manufacturing of ethanol, the main ingredient in flex fuels (e85). in order to produce
a large corn crop, you need to purchase a fertlizer that is high in nitrogen. given the
choice of two fertlizers, ammonium sulfate or ammonium phosphate, which one
would you choose to yield the largest amount of corn? explain your answer. hint:
determine the percent of nitrogen in each fertilizer.

Answers

Based on the nitrogen content, you should choose ammonium phosphate as it contains a higher percentage of nitrogen (28.2%) compared to ammonium sulfate (21.2%), which will potentially yield a larger corn crop for ethanol production.

To determine which fertilizer, ammonium sulfate or ammonium phosphate, would yield the largest amount of corn for ethanol production, you need to consider the nitrogen content in each fertilizer.

Ammonium sulfate has the chemical formula (NH4)2SO4. It contains 2 nitrogen atoms (N), 8 hydrogen atoms (H), 1 sulfur atom (S), and 4 oxygen atoms (O). The molar mass of nitrogen is 14 g/mol, so the nitrogen content in ammonium sulfate is:
2(N) = 2(14 g/mol) = 28 g/mol.

The molar mass of ammonium sulfate is 132.14 g/mol. To calculate the percent of nitrogen in ammonium sulfate, divide the nitrogen mass by the total molar mass and multiply by 100:
(28 g/mol) / (132.14 g/mol) × 100 = 21.2%.

Ammonium phosphate has the chemical formula (NH4)3PO4. It contains 3 nitrogen atoms, 12 hydrogen atoms, 1 phosphorus atom, and 4 oxygen atoms. The nitrogen content in ammonium phosphate is:
3(N) = 3(14 g/mol) = 42 g/mol.

The molar mass of ammonium phosphate is 149.09 g/mol. To calculate the percent of nitrogen in ammonium phosphate, divide the nitrogen mass by the total molar mass and multiply by 100:
(42 g/mol) / (149.09 g/mol) × 100 = 28.2%.

Based on the nitrogen content, you should choose ammonium phosphate as it contains a higher percentage of nitrogen (28.2%) compared to ammonium sulfate (21.2%), which will potentially yield a larger corn crop for ethanol production.

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NEED HELP FAST!!!! Please answer both questions

Answers

The molarity is 0.37 M

The molality is 1.71 m

What is molarity?

Molarity is a unit of concentration used to measure the amount of a solute in a solution. It is defined as the number of moles of solute dissolved per liter of solution (mol/L). In other words, molarity tells us how many moles of solute are present in each liter of solution.

The formula for calculating molarity is:

Molarity (M) = moles of solute ÷ volume of solution in liters

Molarity = 100g/180 g/mol * 1/1.5 L

= 0.37 M,

Molality = 200g/58.5g/mol * 1/2 Kg

1.71 m

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An object in motion stays in motion and an object at rest stays at rest until ?

Answers

An object in motion will continue to move at a constant velocity unless acted upon by an external force. This principle is known as Newton's First Law of Motion, also referred to as the law of inertia.

Inertia is the tendency of an object to resist changes in its state of motion.

Similarly, an object at rest will remain at rest unless acted upon by an external force. This means that if an object is not moving, it will continue to stay still until a force is applied to it.

Newton's First Law of Motion is a fundamental concept in physics that explains how objects behave when in motion or at rest. It is important to understand this law because it helps us to predict how objects will move and interact with each other.

Additionally, it is also essential in the design and engineering of machines and structures that require a thorough understanding of motion and force.

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Certain amounts of the hypothetical substances A2 and B are mixed in a 3. 00 liter container at 300. K. When equilibrium is established for the reaction the following amounts are present: 0. 200 mol of A2, 0. 400 mol of B, 0. 200 mol of D, and 0. 100 mol of E. What is Kp, the equilibrium constant in terms of partial pressures, for this reaction

Answers

Without knowing the balanced chemical equation for the reaction involving A2, B, D, and E, it is not possible to determine the equilibrium constant Kp.

The equilibrium constant Kp is specific to a particular chemical reaction at a given temperature, and is determined by the stoichiometry of the reaction and the relative partial pressures of the reactants and products at equilibrium.

Therefore, to calculate Kp, we need to know the balanced chemical equation for the reaction involving A2, B, D, and E, as well as the partial pressures of the gases at equilibrium.

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What type of acid-base reactions are solely defined by how protons are given up or are taken?
what is a hydroxide ion?
what two products do all acid-base neutralization reactions produce
calculate the ph of a 0.25m solution of h3o+
calculate the ph of a 6.3x10-8m solution of h3o+
look at your answer for 4 and 5 which one is a base?
look at 4 and 5 which one is a strong acid

Answers

Type of Acid-Base Reactions: Acid-Base Neutralization Reactions. A hydroxide ion (OH-) is an anion with a single hydrogen atom and two oxygen atoms.

What is hydrogen ?

Hydrogen is the lightest of all elements, and is a colorless, odorless, tasteless, non-metallic gas. It is the most abundant element in the universe, making up around 75% of all matter. Hydrogen has three isotopes: protium (the most common), deuterium, and tritium. Hydrogen is found on Earth in compounds of other elements, such as water (H2O), and in hydrocarbons, such as natural gas (CH4). It is a key component of many fuels and can be used to generate electricity through fuel cells.

All acid-base neutralization reactions produce a salt and water. The salt will depend on the acid and base used in the reaction.The pH of a 0.25M solution of H3O+ is 0.The pH of a 6.3x10-8M solution of H3O+ is 7.21.The pH of 0.25M solution of H3O+ (0) is a base, while the pH of 6.3x10-8M solution of H3O+ (7.21) is neutral.The pH of 0.25M solution of H3O+ (0) is a strong acid, while the pH of 6.3x10-8M solution of H3O+ (7.21) is a weak acid.

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If 124. 67 grams of KOH can be created by 40. 0 grams of water and 75. 00 grams


were actually created, what is the percent yield?

Answers

The percent yield of KOH is 60.26%.

To calculate the percent yield, we first need to find the theoretical yield and then compare it with the actual yield. In this case, the actual yield is given as 75.00 grams.

1. Find moles of water (H2O):
40.0 g H2O × (1 mol H2O / 18.02 g H2O) = 2.2198 mol H2O

2. Use the balanced chemical equation to find moles of KOH:
H2O + KO → KOH + 1/2 H2
From the balanced equation, 1 mol of H2O produces 1 mol of KOH. Thus,
2.2198 mol H2O × (1 mol KOH / 1 mol H2O) = 2.2198 mol KOH

3. Find the theoretical mass of KOH:
2.2198 mol KOH × (56.11 g KOH / 1 mol KOH) = 124.44 g KOH

Now that we have the theoretical yield (124.44 g KOH) and the actual yield (75.00 g KOH), we can calculate the percent yield:

Percent Yield = (Actual Yield / Theoretical Yield) × 100
Percent Yield = (75.00 g KOH / 124.44 g KOH) × 100 = 60.26%

So, the percent yield of KOH is 60.26%.

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Find the mass of 50% CaCO3 which will produce
136 g of CaSO4? (Molar mass of CaCO3 = 100 g;
Molar mass of CaSO4 = 136 g)
CaCO3 + H2SO4 → CaSO4 + H2O + CO2
(1) 100 g (2) 200 g
(3) 300 g (4) 400 g

Answers

Answer:

Explanation:

From the balanced chemical equation, we can see that one mole of CaCO3 reacts with one mole of CaSO4. Therefore, we can use the molar mass of CaCO3 and the given amount of CaSO4 to calculate the amount of CaCO3 needed, and then convert it to mass.

Number of moles of CaSO4 = Mass / Molar mass

Number of moles of CaSO4 = 136 / 136

Number of moles of CaSO4 = 1

Since the reaction is 1:1, the number of moles of CaCO3 required is also 1. Therefore, we can use the molar mass of CaCO3 to calculate the mass required:

Mass of CaCO3 = Number of moles x Molar mass

Mass of CaCO3 = 1 x 100

Mass of CaCO3 = 100 g

Therefore, the answer is (1) 100 g.

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CHEMISTRY HELP NEEDED IMMEDIATELY PLEASE !! I need all questions answered by tonight, please. Someone help

How many grams of oxygen would be needed to react with 4.06 grams of carbon tetrahydride? Balanced Equation: _______________________________________________________
2. How many grams of oxygen would be produced from the decomposition of 12.3 grams of sulfur trioxide?
Balanced Equation: _______________________________________________________

3. How many grams of potassium would be needed to synthesize 34 grams of potassium chloride? Balanced Equation: _______________________________________________________
4. A lab technician combusts 15.0 grams of octane (C8H18) with excess oxygen and is able to recover 44.7 grams of carbon dioxide gas. Calculate the percent yield for this process. Hint: You must balance the equation first!
C8H18 + O2 → CO2 + H2O
---------------------------------------------------------------------------------------------------------------------------------------------------
ANS KEY (in random order):

1. ) 16.3 g O2
2.) 7.37 g O2
3.) 18 g K
4.) 92.3% (48.4g CO2)

Answers

The mass of oxygen is 16 g

The mass of oxygen is 2.4 g

What is the stoichiometry?

We know from the balanced reaction equation that;

[tex]CH_{4}[/tex]+ 2[tex]O_{2}[/tex] ---> [tex]CO_{2}[/tex] + 2[tex]H_{2} O[/tex]

Number of moles of[tex]CH_{4}[/tex] = 4.06 g/16 g/mol

= 0.25 moles

If 1 mole of [tex]CH{4}[/tex] reacts with 2 moles of[tex]O_{2}[/tex]

0.25 moles of [tex]CH_{4}[/tex] reacts with 0.25 * 2/1

= 0.5 moles

Mass of the oxygen = 0.5 moles * 32 g/mol

= 16 g

The balanced reaction equation is;

2S[tex]O_{3}[/tex](g)⇋2S[tex]O_{2}[/tex](g)+[tex]O_{2}[/tex](g)

Number of moles of sulfur trioxide = 12.3 g/80 g/mol

= 0.15 moles

If 2 moles of S[tex]O_{3}[/tex] produces 1 mole of oxygen

0.15 moles ofS[tex]O_{3}[/tex]will produce 0.15 * 1/2

= 0.075 moles

Mass of oxygen = 0.075 moles * 32 g/mol

= 2.4 g

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What is the molar concentration of a solution formed when. 55 mol of Ca(OH)2 are dissolved in 2. 20 liters of HOH?

Answers

The molar concentration of the solution is 0.25 M.

The molar concentration of a solution, also known as molarity, is defined as the number of moles of solute per liter of solution.

In this case, the amount of Ca(OH)2 dissolved is 0.55 mol and the volume of water used is 2.20 L. Therefore, the molar concentration can be calculated using the formula:

Molarity = moles of solute / volume of solution in litersMolarity = 0.55 mol / 2.20 LMolarity = 0.25 M

Hence, the molar concentration of the solution is 0.25 M.

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How many degrees will the air temperature be different in 2050 from the air temperature in 2000? (Your answer should be a number or range of numbers. )

Answers

The air temperature difference in 2050 from 2000 could be 1.8 - 4.0 degrees Celsius.

What is temperatures?

Temperatures refer to the degree of hotness or coldness of a substance or environment. Temperatures are usually measured with thermometers, which measure the thermal energy of a system. Temperatures can be measured in Fahrenheit, Celsius, or Kelvin. In general, temperatures tend to increase as the amount of thermal energy in a system increases.

It is impossible to accurately predict the exact air temperature difference in 2050 from 2000 without more information. However, it is estimated that the global average temperature could increase anywhere from 1.8 - 4.0 degrees Celsius by 2050, compared to pre-industrial levels. Therefore, a reasonable range of the air temperature difference in 2050 from 2000 could be 1.8 - 4.0 degrees Celsius.

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The industrial production of hydroiodic acid takes place by treatment of iodine with hydrazine N2H4: 2I2 + N2H4 = 4HI + N2 a) how many grams of I2 needed to react with 36. 7 g of N2H4? b) how many grams of HI are produced from the reaction of 115. 7 g of N2H4 with excess iodine?

Answers

a) To determine the number of grams of I2 needed to react with 36.7 g of N2H4, we need to use stoichiometry.

The balanced equation for the reaction is:

2I2 + N2H4 → 4HI + N2

From the equation, we can see that 2 moles of I2 react with 1 mole of N2H4 to produce 4 moles of HI. So, the mole ratio of I2 to N2H4 is 2:1.

First, we need to determine the number of moles of N2H4 in 36.7 g:

moles of N2H4 = mass / molar mass

moles of N2H4 = 36.7 g / 32.045 g/mol

moles of N2H4 = 1.146 mol

Since the mole ratio of I2 to N2H4 is 2:1, we need half as many moles of I2 as there are moles of N2H4:

moles of I2 = 1.146 mol / 2

moles of I2 = 0.573 mol

Finally, we can calculate the number of grams of I2 needed:

mass of I2 = moles of I2 x molar mass of I2

mass of I2 = 0.573 mol x 253.81 g/mol

mass of I2 = 145.5 g

Therefore, 145.5 grams of I2 are needed to react with 36.7 grams of N2H4.

b) To determine the number of grams of HI produced from the reaction of 115.7 g of N2H4 with excess iodine, we need to use stoichiometry again.

The balanced equation for the reaction is:

2I2 + N2H4 → 4HI + N2

From the equation, we can see that 2 moles of I2 react with 1 mole of N2H4 to produce 4 moles of HI. So, the mole ratio of HI to N2H4 is 4:1.

First, we need to determine the number of moles of N2H4 in 115.7 g:

moles of N2H4 = mass / molar mass

moles of N2H4 = 115.7 g / 32.045 g/mol

moles of N2H4 = 3.609 mol

Since the mole ratio of HI to N2H4 is 4:1, we can calculate the number of moles of HI produced:

moles of HI = 4 x moles of N2H4

moles of HI = 4 x 3.609 mol

moles of HI = 14.436 mol

Finally, we can calculate the number of grams of HI produced:

mass of HI = moles of HI x molar mass of HI

mass of HI = 14.436 mol x 127.91 g/mol

mass of HI = 1846.5 g

Therefore, 1846.5 grams of HI are produced from the reaction of 115.7 grams of N2H4 with excess iodine.

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Determine the concentration of 24.5 grams of cesium hydroxide in 100.0 mL of water.

Answers

Answer:

This data gives a relationship between amount of solute and volume of solution: 5.67 g KCl /. 100.0 mL. To find molarity we must convert grams KCl to moles hope this helps

Explanation:

What is the volume of 34. 6 mol O2 at 2. 5 atm and 30 oC?

Answers

The answer is  is approximately 344.16 L.

To find the volume of 34.6 mol O2 at 2.5 atm and 30°C, we can use the Ideal Gas Law equation: PV = nRT.

In this equation:
P = pressure (2.5 atm)
V = volume (which we need to find)
n = moles of gas (34.6 mol O2)
R = ideal gas constant (0.0821 L atm/mol K)
T = temperature in Kelvin (30°C + 273.15 = 303.15 K)

Rearrange the equation to solve for V: V = nRT / P

Now, plug in the values: V = (34.6 mol)(0.0821 L atm/mol K)(303.15 K) / (2.5 atm)

Calculate the volume: V ≈ 344.16 L

The volume of 34.6 mol O2 at 2.5 atm and 30°C is approximately 344.16 L.

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What mass of copper (II) sulfate was in the hydrate? Show your work or explain your reasoning

Answers

To determine the mass of copper (II) sulfate in the hydrate, we need to understand the concept of a hydrate. A hydrate is a compound that has water molecules bound to it. Copper (II) sulfate is a hydrate, meaning it has water molecules attached to it. To find the mass of copper (II) sulfate in the hydrate, we need to remove the water molecules from the compound and calculate the remaining mass of the anhydrous salt.

To do this, we need to use the molar mass of the hydrate and the molar mass of the anhydrous salt. The molar mass of copper (II) sulfate pentahydrate is 249.68 g/mol, and the molar mass of anhydrous copper (II) sulfate is 159.61 g/mol. This means that the water molecules in the hydrate account for 90.07 g/mol of the total mass.

Now, let's assume we have 5 grams of the hydrate. We can use this information to calculate the mass of copper (II) sulfate in the hydrate. First, we need to calculate the number of moles of the hydrate by dividing the mass by the molar mass:

5 g / 249.68 g/mol = 0.02002 mol
Next, we need to calculate the number of moles of water in the hydrate by multiplying the total number of moles by the molar mass of water:

0.02002 mol x 18.015 g/mol = 0.3609 g
Finally, we can calculate the mass of anhydrous copper (II) sulfate by subtracting the mass of water from the total mass of the hydrate:
5 g - 0.3609 g = 4.6391 g

Therefore, the mass of copper (II) sulfate in the hydrate is:

4.6391 g * (159.61 g/mol / 249.68 g/mol) = 2.9647 g

In conclusion, to find the mass of copper (II) sulfate in the hydrate, we need to subtract the mass of water from the total mass of the hydrate and then convert the remaining mass to the mass of anhydrous copper (II) sulfate.

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The following reaction is done at stp:
n2 (g) + 3 h 2 (g) à 2 nh 3 (g)

if i.5 l of nitrogen gas are added to an excess of hydrogen gas, how many liters of nh3 gas will form?

Answers

At STP, 1.5 L of nitrogen gas will produce 3 L of NH₃ gas.

The balanced chemical equation for the reaction is N₂(g) + 3H₂(g) --> 2NH₃(g). According to the stoichiometry, 1 mole of nitrogen gas (N₂) reacts with 3 moles of hydrogen gas (H₂) to produce 2 moles of ammonia gas (NH₃). At STP, the volume of one mole of any gas is 22.4 L.

Step 1: Calculate the moles of N₂ in 1.5 L.
Moles of N₂ = (Volume of N₂ / 22.4 L/mol) = 1.5 L / 22.4 L/mol = 0.067 moles.

Step 2: Use the stoichiometry to find the moles of NH₃ formed.
Moles of NH₃ = 2 * Moles of N₂ = 2 * 0.067 moles = 0.134 moles.

Step 3: Calculate the volume of NH₃ formed at STP.
Volume of NH₃ = (Moles of NH₃ * 22.4 L/mol) = 0.134 moles * 22.4 L/mol = 3 L.

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5. Compare the mass of the reactants and the mass of the products in a chemical reaction, and explain how these masses are related

Answers

According to the law of conservation of mass, the total mass of the reactants in a chemical reaction is equal to the total mass of the products.

This means that the mass of the reactants before the reaction is the same as the mass of the products after the reaction. In other words, mass is neither created nor destroyed during a chemical reaction, it is only transformed from the reactants into the products.

Therefore, the masses of the reactants and the products in a chemical reaction are directly related and must balance each other. This relationship is fundamental in chemistry and is used to calculate the amount of reactants and products in a chemical reaction, as well as to predict the outcome of the reaction.

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which of the following characteristics would be preferred for a better resonance structure? select the correct answer below: minimal formal charges maximized bond strength negative formal charges on the most electronegative atom all of the above

Answers

The characteristic that would be preferred for a better resonance structure is maximized bond strength. Option B is correct.

Maximizing bond strength is a crucial characteristic for a better resonance structure because it leads to a more stable structure. Resonance structures are a set of contributing structures that show the delocalization of electrons in a molecule. These structures should have similar energies and contribute equally to the actual structure of the molecule. The more stable a resonance structure, the greater its contribution to the actual structure.

Formal charges are important for resonance structures, but a minimal formal charge or negative formal charges on the most electronegative atom are not the only factors that contribute to a better resonance structure. In fact, some resonance structures may have formal charges that are not minimized or negative formal charges on less electronegative atoms.

Maximizing bond strength ensures that the structure is stable and contributes significantly to the actual structure of the molecule. Therefore, maximizing bond strength is the most important characteristic for a better resonance structure. Option B is correct.

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Find the volume of a figure round the answer to the nearest hundred 4cm 4cm 4cm

Answers

Answer: 64 I think

Explanation:

unsure of wether or not there is a specific shape given but the original equation for volume is length x width x height so just multiply all..

4 x 4 = 16

16 x 4 = 64

What hybridization would you expect for se when it is found in seo42-?.

Answers

When selenium (Se) is found in the compound SEO42-, it has undergone hybridization to form sp3 hybrid orbitals.

Hybridization is the process by which atomic orbitals of different energy levels combine to form hybrid orbitals with the same energy level. In SEO42-, the Se atom is bonded to four oxygen (O) atoms, and to form these bonds, the Se atom has to hybridize its orbitals.

In its ground state, Se has six valence electrons in its outermost shell - two in the 4s orbital and four in the 4p orbital. To form the four bonds with O, Se hybridizes its orbitals by promoting an electron from the 4s orbital to the 4p orbital. This gives Se four half-filled 4p orbitals, which then hybridize to form four sp3 hybrid orbitals.

Each of these hybrid orbitals is then used to form a sigma bond with one of the four O atoms.

In summary, when Se is found in SEO42-, it undergoes sp3 hybridization to form four sp3 hybrid orbitals, each of which is used to form a sigma bond with one of the four O atoms. This hybridization results in a tetrahedral arrangement of the atoms around the Se atom in the molecule.

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What is the normal boiling point of a 3.45mol solution of kbr that has density of 1.10gml?(ka for h2o is 0.512°c kg/mole)

Answers

The normal boiling point of the 3.45 mol solution of KBr is 104.7384°C.

The normal boiling point of a 3.45 mol solution of KBr with a density of 1.10 g/mL can be calculated using the formula:

ΔT = Kb * molality

where ΔT is the boiling point elevation, Kb is the molal boiling point elevation constant for water (0.512°C kg/mol), and molality is the number of moles of solute per kilogram of solvent.

First, we need to calculate the mass of the solvent (water) required to dissolve 3.45 mol of KBr. The molar mass of KBr is 119 g/mol, so 3.45 mol of KBr would weigh 409.55 g.

Since the density of the solution is given as 1.10 g/mL, the volume of the solution is:

V = m / ρ = 409.55 g / 1.10 g/mL = 372.32 mL

So, the mass of the water is:

mH2O = V * ρH2O = 372.32 mL * 1 g/mL = 372.32 g

The molality of the solution can be calculated as follows:

molality = moles of solute / mass of solvent (in kg) = 3.45 mol / 0.37232 kg = 9.27 mol/kg

Substituting the values in the formula for boiling point elevation:

ΔT = 0.512°C kg/mol * 9.27 mol/kg = 4.7384°C

The normal boiling point of pure water is 100°C, so the boiling point of the KBr solution would be:

Boiling point = 100°C + ΔT = 100°C + 4.7384°C = 104.7384°C

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_____KOH (aq) + ____H3PO4 (aq) → ___K3PO4 (aq) + __H2O (l)

Chemical equations must be balanced to satisfy the _____

A. law of definite proportions

B. principle of Avogadro

C. law of conservation of mass

D. law of multiple proportions

Answers

Answer: C. law of conservation of mass

Explanation:

Explain with words how the parent nucleus’s changes in gamma decay

Answers

The changes that occur in the parent nucleus during gamma decay are limited to the emission of a gamma ray and the associated decrease in energy. The mass and atomic number of the nucleus remain unchanged.

In gamma decay, the parent nucleus does not undergo any changes in terms of its mass or atomic number. Instead, the nucleus emits a gamma ray, which is a high-energy photon. This gamma ray is released as the nucleus transitions from an excited state to a lower energy state.

The emission of a gamma ray does not affect the number of protons or neutrons in the nucleus. This means that the atomic number and mass number of the nucleus remain the same before and after gamma decay.

However, the emission of a gamma ray does result in a decrease in the energy of the nucleus. This is because gamma rays have a very high frequency and carry a lot of energy. By releasing a gamma ray, the nucleus is able to shed some of this excess energy and move to a lower energy state.

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57.49 g of HCl (aq) reacting with 98.20 g of AgNO3(aq) will produce how many grams of AgCl (s) precipitate?​

Answers

57.49 g of HCl reacting with 98.20 g of [tex]AgNO_3[/tex] will produce 62.3 g of AgCl precipitate.

To determine the grams of AgCl (s) precipitate produced, we first need to write and balance the chemical equation for the reaction between hydrochloric acid (HCl) and silver nitrate ([tex]AgNO_3[/tex]) that produces silver chloride (AgCl) precipitate:

HCl (aq) + [tex]AgNO_3[/tex]  (aq) → AgCl (s) + [tex]HNO_3[/tex] (aq)

From the balanced equation, we can see that one mole of [tex]AgNO_3[/tex] reacts with one mole of HCl to produce one mole of AgCl.

To determine the limiting reactant in the reaction, we need to calculate the number of moles of each reactant:

moles of HCl = 57.49 g / 36.46 g/mol = 1.577 mol

moles of [tex]AgNO_3[/tex] = 98.20 g / 169.87 g/mol = 0.578 mol

Since [tex]AgNO_3[/tex] has fewer moles than HCl, it is the limiting reactant. This means that all of the [tex]AgNO_3[/tex] will be consumed in the reaction, and any excess HCl will be left over.

The number of moles of AgCl produced can be calculated from the number of moles of [tex]AgNO_3[/tex] :

moles of AgCl = moles of [tex]AgNO_3[/tex] = 0.578 mol

The mass of AgCl produced can be calculated using the molar mass of AgCl:

mass of AgCl = moles of AgCl x molar mass of AgCl

mass of AgCl = 0.578 mol x (107.87 g/mol) = 62.3 g

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Explain why I2 is a solid, Br2 is a liquid but Cl2and F2 are gases even though they are all Halogens

Answers

I₂ is a solid, Br₂ is a liquid, while Cl₂ and F₂ are gases because of their increasing molecular size and decreasing strength of their intermolecular forces.

The main factor influencing the physical states of halogens is the strength of the intermolecular forces (Van der Waals forces) between their molecules.

As you move down Group 17 in the periodic table (from F₂ to I₂), the size and mass of the halogen molecules increase. Larger molecules have a greater number of electrons, leading to stronger dispersion forces (a type of Van der Waals forces) between molecules.

For I₂, these forces are strong enough to hold the molecules together in a solid form. For Br₂, the forces are slightly weaker but still strong enough to form a liquid. However, in Cl₂ and F₂, the forces are weaker, allowing the molecules to be in a gaseous state at room temperature.

In summary, the physical states of the halogens depend on the strength of their intermolecular forces, which is influenced by the size and mass of the molecules.

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A gas occupying 3. 05 liters at STP is warmed to 85. 0°C. It


now occupies 9. 85 liters. What is the pressure of the gas?

Answers

The pressure of the gas can be calculated using the combined gas law equation. The pressure of the gas at STP is 1 atm. Therefore, the pressure of the gas at 85.0°C is 0.289 atm.

Given that a gas occupies 3.05 L at STP, we can assume that the gas is at a pressure of 1 atm and a temperature of 273 K. We can use the ideal gas law to find the number of moles of gas in the container at STP:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin.

Rearranging the equation to solve for n, we get:

n = PV/RT

Substituting in the values for P, V, R, and T, we get:

n = (1 atm)(3.05 L)/(0.0821 L·atm/mol·K)(273 K)

n = 0.125 mol

Now, we know that the volume of the gas has increased to 9.85 L and the temperature has increased to 85°C. We need to find the new pressure of the gas.

First, we need to convert the temperature to Kelvin:

85°C + 273 = 358 K

Next, we can use the combined gas law to find the new pressure of the gas:

P1V1/T1 = P2V2/T2

Substituting in the values we know:

(1 atm)(3.05 L)/(273 K) = P2(9.85 L)/(358 K)

Solving for P2, we get:

P2 = (1 atm)(3.05 L)/(273 K)(9.85 L/358 K)

P2 = 0.289 atm

Therefore, the pressure of the gas at the new volume and temperature is 0.289 atm.

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Predict the phenotypic and genotypic outcome (offspring) of a cross betweenn

two plants heterozygous for round peas

Answers

The predicted phenotypic outcome of this cross will be that 75% of the offspring will have a round phenotype, while 25% will have a wrinkled phenotype.

To predict the phenotypic and genotypic outcome of a cross between two plants heterozygous for round peas, we need to first understand the genetics involved.

Round peas are dominant over wrinkled peas, which means that the genotype for round peas can be either homozygous dominant (RR) or heterozygous (Rr), while the genotype for wrinkled peas is homozygous recessive (rr).

When two plants heterozygous for round peas are crossed (Rr x Rr), there are three possible genotypic outcomes for their offspring: RR, Rr, or rr. However, because round peas are dominant, any offspring with at least one R allele (RR or Rr) will have a round phenotype.

Therefore, the predicted phenotypic outcome of this cross will be that 75% of the offspring will have a round phenotype, while 25% will have a wrinkled phenotype. The predicted genotypic outcome will be that 25% of the offspring will be homozygous dominant (RR), 50% will be heterozygous (Rr), and 25% will be homozygous recessive (rr).

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The separation of benzene (B) from cyclohexane (C) by distillation at 1 atm is impossible because of a minimum-boiling-point azeotrope at 54. 5 mol% benzene. However, extractive distillation with furfural is feasible. For an equimolar feed, cyclohexane and benzene products of 98 and 99 mol%, respectively, can be produced. Alternatively, the use of a three-stage pervaporation process, with selectivity for benzene using a polyethylene membrane, has received attention, as discussed by Rautenbach and Albrecht [47]. Consider the second stage of this process, where the feed is 9,905 kg/h of 57. 5 wt% B at 75C. The retentate is 16. 4 wt% benzene at 67. 5C and the permeate is 88. 2 wt% benzene at 27. 5C. The total permeate mass flux is 1. 43 kg/m2-h and selectivity for benzene is 8. Calculate flow rates of retentate and permeate in kg/h and membrane surface area in m2

Answers

The retentate flow rate is 5,021.862 kg/h and the permeate flow rate is 5,021.862 kg/h. The membrane surface area required is 3,517.948 m².

What is permeate flow ?

Permeate flow is the rate at which a fluid passes through a membrane. It is a measure of the membrane's permeability, which is the ability of a substance to pass through a membrane. Permeate flow is used in many industrial processes, such as purification of fluids, separation of compounds, and concentration of liquids.

The first step is to calculate the mass flow rate of the feed. This is given by the equation:

Mass flow rate (kg/h) = Feed flow rate (kg/h) x Feed concentration (wt%)

Mass flow rate = 9,905 kg/h x 57.5 wt% = 5,686.625 kg/h

Next, we need to calculate the flow rate of the retentate and permeate in kg/h. This is given by the equation:

Flow rate (kg/h) = Mass flow rate (kg/h) x Retentate/Permeate concentration (wt%)

Retentate flow rate = 5,686.625 kg/h x 16.4 wt% = 931.939 kg/h

Permeate flow rate = 5,686.625 kg/h x 88.2 wt% = 5,021.862 kg/h

Finally, we need to calculate the membrane surface area in m². This is given by the equation:

Membrane surface area (m²) = Permeate flow rate (kg/h) / Total permeate mass flux (kg/m²-h)

Membrane surface area = 5,021.862 kg/h / 1.43 kg/m²-h = 3,517.948 m².

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How much heat is released when a 27. 7 g sample of ethylene glycol (C = 2. 42 J/gºC) at 42. 76°C is cooled to


32. 5°C

Answers

When a 27. 7 g sample of ethylene glycol (C = 2. 42 J/gºC) at 42. 76°C is cooled to 32. 5°C the amount of heat released is  685.87 joule.

To calculate the heat released when a 27.7 g sample of ethylene glycol is cooled from 42.76°C to 32.5°C, you can use the formula:

q = mcΔT

where q represents the heat released, m is the mass (27.7 g), c is the specific heat capacity (2.42 J/gºC), and ΔT is the change in temperature (42.76°C - 32.5°C).

ΔT = 42.76°C - 32.5°C = 10.26°C

Now plug in the values into the formula:

q = (27.7 g) × (2.42 J/gºC) × (10.26°C) = 685.87 J

So, 685.87 Joules of heat are released when the 27.7 g sample of ethylene glycol is cooled from 42.76°C to 32.5°C.

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