How to set up the rate expressions for the following mechanism?

A → B k1
B → A k2
B+C → D k3

If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to derive the rate law. Derive the rate law, and show that this reaction may follow the first-order equation at high pressures and the second-order equation at low pressures.

Answers

Answer 1

Answer:

Explanation:

From the given information:

A → B k₁

B → A k₂

B + C → D k₃

The rate law = [tex]\dfrac{d[D]}{dt}=k_3[B][C] --- (1)[/tex]

[tex]\dfrac{d[B]}{dt}=k[A] -k_2[B] -k_3[B][C][/tex]

Using steady-state approximation;

[tex]\dfrac{d[B]}{dt}=0[/tex]

[tex]k_1[A]-k_2[B]-k_3[B][C] = 0[/tex]

[tex][B] = \dfrac{k_1[A]}{k_2+k_3[C]}[/tex]

From equation (1), we have:

[tex]\mathbf{\dfrac{d[D]}{dt}= \dfrac{k_3k_1[A][C]}{k_2+k_3[C]}}[/tex]

when the pressure is high;

k₂ << k₃[C]

[tex]\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_3[C]}= k_1A \ \ \text{first order}[/tex]

k₂ >> k₃[C]

[tex]\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_2}= \dfrac{k_1k_3}{k_2}[A][C] \ \ \text{second order}[/tex]


Related Questions

Consider two compounds. Compound A contains 15.7 g of sulfur and 18.6 g of fluorine. Compound B contains 25.4 g of sulfur and 60.2 g of fluorine. For Compound A, the ratio of fluorine to sulfur is 1.18. For Compound B, the ratio of fluorine to sulfur is 2.37. Using the Law of Definite Proportions (also called the Law of Constant Composition), could Compound A and Compound B be the same compound

Answers

Answer:

No, compound A and B are not the same compound

Explanation:

According to the law of definite proportion "every chemical compound contains fixed and constant proportions (by mass) of its constituent elements." (Encyclopedia Britannica)

We can see in the question that the ratio of flourine to sulphur in compound A is 1.18 while the ratio of flourine to sulphur in compound B is 2.37.

The two chemical compounds do not contain a fixed proportion by mass of their constituent elements therefore, they can not be same compound according to the law of definite proportions.

write down four fuctions of water learned in life sciences class​

Answers

Answer:

See explanation

Explanation:

Water is a polar solvent and is also called a universal solvent because of its ability to dissolve several substances especially in the body.

The functions of water learned in the life sciences class include;

1. Water is the medium for biochemical reactions

2. Most substances in the body are transported from place to place by water.

3. Water acts a solvent for many biologically important substances in the body.

4. Water is necessary in helping animals to regulate their body temperature.

A chemist determined by measurements that 0.060 moles of silver participated in a chemical reaction. Calculate the mass of silver that participated in the chemical reaction.
Be sure your answer has the correct number of significant digits.

Answers

Answer:

its your first question like imagine your literally so free so dog water like you have no earnings i am first place in fncs you was 6 th where were you your boxed like a fish eat this pump.

Explanation:

1. What is the frequency of the following:
a. radio waves with wavelength 50 m?
b. gamma-ray with a wavelength of 45 m?
2.What is the wavelength of the following?
a. infrared light with frequency of 3 .5x 10° Hz?
b. ultraviolet light with frequency of 4.0x 10 * Hz​

Answers

Answer:

its soooooo ezy

Explanation:

82828I 87is 818373773622771829383746171948468328933737373737378364737272828374736367181i3i46738100104848070792761527484930201834728the 8585949476425675666

A student knows that hydrogen (H) atoms and oxygen (O) atoms combine to form water (H2O). The student correctly predicts that hydrogen (H) and sulfur (S) will combine to form hydrogen sulfide (H2S) On what is this prediction most likely based?

A. Oxygen and sulfur are in the same family with the same number of valence electrons.
B. Oxygen and sulfur are in the same period or row with the same number of neutrons
C. Oxygen and sulfur are in the same period or row with the same number of protons
D. Oxygen and sulfur are in the same family with the same number of energy levels.

Answers

Answer:

A

Explanation:

They both need to lose 2 electrons to form ions

Oxygen and sulphur are in the same family with the same number of valence electrons.

What is meant by valence electron?

The electrons in an atom's outermost shell, or energy level, are called valence electrons.

Compared to oxygen, sulphur has more electron shells. This is because sulphur has three electron shells because it is in period 3 of the periodic table, whereas oxygen is in period 2 and has two electron shells.

Since there is just one link between these oxygen atoms, they will each have six valence electrons and a shared valence electron with sulphur.

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From what did Oceans form?

Answers

Answer:

God

Explanation:

What is the main FUNCTION of the digestive system?
What are some of the main organs of the digestive system?

Answers

The main function of the digestive system is to break food down

What is the density of nitrogen gas at 356.4 K?

Answers

Answer:

Nitrogen gas (chemical symbol N) is generally inert, nonmetallic, colorless, odorless and tasteless. Its atomic number is 7, and it has an atomic weight of 14.0067. Nitrogen has a density of 1.251 grams/liter at 0 C and a specific gravity of 0.96737, making it slightly lighter than air.

Explanation:

:)

It is the highest point in a wave.​

Answers

Answer:

Crest is the highest point of a wave

Can you think of an example where hydrogen and oxygen combine and release energy with little or no release of heat energy?

Answers

a flame from a match or a spark breaks some of the bonds, the resulting oxygen and carbon atoms react to release energy and keep a fire going until it runs out of fuel.

When hydrogen and oxygen combine, they form water or hydrogen peroxide, and energy is released in the process.

What are oxygen and hydrogen?

Oxygen and hydrogen are the chemical elements of the periodic table, and they both are gas. Oxygen is the most important gas, which is needed for breathing. It is present at 21% in the atmosphere.

Hydrogen is another gas present in nature. It is the lightest gas, and it has diatomic molecules. It remains gas at normal pressure and temperature, but it becomes liquid at low temperature.

The oxygen and hydrogen readily react and for water, and hydrogen peroxide, the process of reaction of hydrogen and oxygen releases an amount of energy.

Hence, Energy is released during the creation of water or hydrogen peroxide when hydrogen and oxygen mix.

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Guys i need help because its due today.

Answers

Answer:

204.6 K

Explanation:

PV = nRT

5.6 (12) = 4 (.0821)T

67.2 = .3284T

204.6 = T

Please solve this i will mark brainlist

Answers

This group has 4 valence electrons
the answer is b , group 14 has 4 valance electrons

A cough syrup has a density of 1.20 g/mL. A doctor orders 48.0 of the syrup for a sick child. How many teaspoons will you administer to the child

Answers

Answer:

because I want to save life

Which of the following are in the human brain?
A. Hypothalamus
B. Pituitary gland.
C. Pineal gland
D. All of them

Answers

The correct answer is D :)
The answer is d(all of them)

what fraction of 2 years is 10 months

Answers

Answer:

10/24

Simplified: 5/12

Explanation:

Well first, let's convert years into months

1 year = 12 months which means 2 years = 24 months

In fraction form we would write this as 10/24

If the question asks for it to be simplified, then simply

Both 10 and 24 evenly fit 2

Therefore, divide both the numerator and the denominator by 2

10 ÷ 2 / 24 ÷ 2

5/12

This can no longer be simplified

Which of the following wavelength does NOT belong to visible light?

A.
690 nm

B.
900 nm

C.
500 nm

D.
390 nm

Answers

Answer:

I think is A 690 nm or c 500 nm

The wavelength that does not belong to visible light is 900 nm. The correct option is B.

What is visible light?

Visible light is the electromagnetic spectrum that an eye can see. The wavelength of visual light is 382 700 nanometers. The daylight is the most visible light whose wavelength is 515 NM and whose color is green and yellow. The infrared, the range of spectrums of visible light, falls between infrared and ultraviolet light.

Wavelength is the distance of 1 wave to another wave full stop as light moves in the form of waves, that difference between one crust to another crust is called the wavelength of the light.

As the wavelength of visible light is 382 700 NM option b 900 NM will be will not fall under the spectrum of visible light.

Thus, the correct option is B. 900 nm.

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Put the following elements in order of increasing atomic number:

1. Strontium
2. Fluorine
3. Terbium
4. Zirconium
5. Iodine
6. Europium
7. Gallium
8. Aluminum

Answers

Answer:

Here is the answer ⬆️⬆️⬆️⬆️⬆️⬆️⬆️

The order of the given elements in increasing atomic number is given as F (9), Al (13), Ga (31), Sr (38), Zr (40), I(53) and Terbium (65).

What is atomic number?

The atomic number of an element in periodic table is the number of electrons in its neutral atom. Elements are arranged in periodic table in an increasing order of atomic number from left to right.

An atom is composed of electrons, protons and neutrons. Protons are positively charged and electrons are negatively charged particles and they are equal in an atom. Thus, the total negative charge is neutralised by the negative charges.

The order for the given elements in periodic table in an increasing atomic number is F (9), Al (13), Ga (31), Sr (38), Zr (40), I(53) and Terbium (65).

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A substance that cannot be broken down into another substance by chemical or physical means is called a

Answers

Answer:

A substance that cannot be broken down into another substance by chemical or physical means is called an Element

dream holiday in sweden essey​

Answers

Answer:

Sweden is the largest of the Nordic countries which are Denmark, Finland, Iceland, Norway, and, of course, Sweden. Sweden's three major cities are Stockholm which is the capital of the country, Gothenburg in the western coast, and Malmö down south.

Sweden is said to have more space to enjoy and relax than most other country. It is a place for people who love to be with nature to seek peace of mind to people who lives by adventure. A perfect vacation spot, Sweden boast of peaceful countryside, lakes and forest, a long coastline of islands good for water sports activities such as sailing and perfect Swedish mountains for skiing during winter. Sweden also has a lot to offer culture vultures and tourist with their rich culture. There are cathedrals and old houses and universities to visit, plus, a smorgasbord of food choices to fill the hungry traveler's stomach. The cities have great pubs and clubs for younger travelers who wants to experience nightlife in Sweden. And there are shopping malls and souvenir shops for everyone to enjoy. Other places of interest are Esrange, a racket launching

facility, Gotland, Sweden's largest island and Kebnekaise, the country's highest mountain.

Answer:

Ferries are sea transport in the form of boat or ship that carries passengers, cargo and sometimes vehicles. It is a type of public transportation that has been around for centuries. It is a cheaper way to travel from one point to another, but lately a trip through a ferry is made not only for financial consideration but for leisure as well. Today's ferries or cruise ships are more efficient and mostly built with the passenger's convenience in mind, and some big ones can accommodate hundreds of passengers, baggage and vehicles in one time. Ferries usually operate on frequent return service. Ferry rides are a relaxing way to travel and to see the sights along the way. One of the world's best ferry destinations is Sweden.

Sweden is the largest of the Nordic countries which are Denmark, Finland, Iceland, Norway, and, of course, Sweden. Sweden's three major cities are Stockholm which is the capital of the country, Gothenburg in the western coast, and Malmö down south.

Sweden is said to have more space to enjoy and relax than most other country. It is a place for people who love to be with nature to seek peace of mind to people who lives by adventure. A perfect vacation spot, Sweden boast of peaceful countryside, lakes and forest, a long coastline of islands good for water sports activities such as sailing and perfect Swedish mountains for skiing during winter. Sweden also has a lot to offer culture vultures and tourist with their rich culture. There are cathedrals and old houses and universities to visit, plus, a smorgasbord of food choices to fill the hungry traveler's stomach. The cities have great pubs and clubs for younger travelers who wants to experience nightlife in Sweden. And there are shopping malls and souvenir shops for everyone to enjoy. Other places of interest are Esrange, a racket launching facility, Gotland, Sweden's largest island and Kebnekaise, the country's highest mountain.

There are just so much outdoor and recreational activities in Sweden, and it is also child-friendly that it has become an ideal family vacation destination. Truly, a trip to Sweden is a rejuvenating experience. But the best way to start the Swedish vacation is by riding a ferry to Sweden.

Riding a Ferry to Sweden

Sweden is a country that can be visited through a ferry from different parts of Europe. There are regular ferry rides from Belgium, Denmark, Estonia, Finland, Latvia, Germany, Norway, Poland, Russia, and United Kingdom. It has become very accessible for travelers and tourist to enjoy the natural beauty and distinct cultural heritage of Sweden. There are a number of sea transport companies that carries passengers, cargo and vehicles that offers regular trips to and from Sweden. Some of the popular ones are Stena Lines, Silja Lines, Birka Cruises, Tallink Lines, Viking Lines, Scandlines, and DFDS. There are ports in major cities of Sweden as well as in Varberg, Helsingborg, Trelleborg, Visby, Ystad among others. Travelers and tourist can book their ferry to Sweden trips through their local travel agents, but they can also conveniently book their travels through the internet.

A luxurious ferry to Sweden usually has suites for honeymooners or multi-cabin that is ideal for family or group of friends making a trip via a ferry an enjoyable experience.

Explanation:

hope it's help you

Which of the following statements about steroid hormones is true?
A. They bind with receptor proteins in the plasma membrane.
B. They bind to carrier proteins in order to be transported in the blood to
their target cells.
C. They are synthesized from epinephrine in the adrenal gland.
D. They are mostly derivatives of the amino acid tyrosine.

Answers

Answer:

B. They bind to carrier proteins in order to be transported in the blood to

their target cells.

Explanation:

Steroid hormones are belongs to the class of chemical compound called steroid. Steroid hormones are majorly secreted by three glands - ovaries, testes and adrenal cortex.

Steroid hormones are released in the blood and are allowed to bind to the specific carrier proteins such as corticosteroid-binding globulin and albumin which helps them to carry to the target cells for the functioning.

The steroid hormone binds to receptor proteins in the target cell and not in the plasma membrane

Hence, the correct answer is "B. They bind to carrier proteins in order to be transported in the blood to  their target cells."

Calculate the percent dissociation of butanoic acid (C3H2CO2H) in a 1.4 mM aqueous solution of the stuff.

Answers

Answer: The percent dissociation of butanoic acid is 9.8%

Explanation:

[tex]C_3H_2CO_2H\rightarrow H^+C_3H_2CO_2^-[/tex]

 cM                                                0             0

[tex]c-c\alpha[/tex]               [tex]c\alpha[/tex]          [tex]c\alpha[/tex]  

So dissociation constant will be:

[tex]K_a=\frac{(c\alpha)^{2}}{c-c\alpha}[/tex]

Give c= 1.4 mM = [tex]1.4\times 10^{-3}[/tex] and [tex]\alpha[/tex] = dissociation constant  

[tex]K_a=1.5\times 10^{-5}[/tex]

Putting in the values we get:

[tex]1.5\times 10^{-5}=\frac{(1.4\times 10^{-3}\times \alpha)^2}{(1.4\times 10^{-3}-1.4\times 10^{-3}\times \alpha)}[/tex]

[tex](\alpha)=0.098=9.8\%[/tex]

Thus percent dissociation of butanoic acid is 9.8%

When drawing a Bohr model for Sulfur, how many energy levels will you
draw?
5
4
3
2.

Answers

Answer:

3

Explanation:

2,8,6

HELPPPPPPP PLZZZ




An apple is growing in the top branches of an apple tree. The stem breaks and the apple falls, moving faster and faster until it hits the ground.

Where is the energy to increase the speed of the apple coming from?



Energy is being created as the apple falls



Energy is not related to the speed of an object



The potential energy the apple had due to its height is converted to kinetic energy



The force from the wind that broke the stem is also pushing the apple down

Answers

Answer:

The potential energy the apple had due to its height is converted to kinetic energy

Explanation:

When an apple falls from the tree to the ground, its energy of position stored as gravitational potential energy is converted to kinetic energy, the energy of motion, as it falls. When the apple hits the ground, kinetic energy is transformed into heat energy.

A 1.00 L of a solution is prepared by dissolving 125.6 g of NaF in it. What would be the molarity of this solution?

Answers

Answer:

2.99 M

Explanation:

In order to solve this problem we need to keep in mind the definition of molarity:

Molarity = moles of solute / liters of solution

In order to calculate the moles of solute, we convert 125.6 g of NaF into moles using its molar mass:

125.6 g NaF ÷ 42 g/mol = 2.99 mol NaF

As the volume is already given, we can proceed to calculate the molarity:

Molarity = 2.99 mol / 1.00 L = 2.99 M

3. If you have 2.6 moles of NaI and 3.9 moles of bromine, how many grams of NaBr can be made from this reaction?
Br2 + NaI → NaBr + I2

Answers

Answer:

0

Explanation:

helllppp pls

Explain how human body maintains normal body temperatur

Answers


Much like a thermostat regulates the temperature inside your home, the hypothalamus regulates your body temperature, responding to internal and external stimuli and making adjustments to keep the body within one or two degrees of 98.6 degrees.

What volume of sulfur dioxide, SO2 (at STP), is

produced by the burning of 0.250 mole of sulfur?

S(s) + O2(g) → SO2(g)

Answers

Answer:

5.6 L is the final volume for SO₂ at STP condtions

Explanation:

The reaction is:  S(s) + O₂ (g) →  SO₂ (g)

Ratio for this reaction is 1:1, if we see stoichiometry.

1 mol of sulfur can react to 1 mol of oxygen in orden to produce 1 mol of sulfur dioxide.

Then, 0.250 moles of sulfur can produce 0.250 moles of SO₂.

If we solve this by a rule of three, we can say:

At STP 1 mol occupies 22.4L

Then, 0.250 moles will be contained at (0.250 mol . 22.4L) /1mol = 5.6 L

If we apply the Ideal Gases Law:

P . V = n . R . T

1 atm . V = 0.250 mol . 0.082 . 273K

V = (0.250 mol . 0.082 . 273K) / 1atm → 5.6 L

Answerroweo'gfnagnas;gns;BGr;kv

Explanation:

At room temperature, CsF is expected to be:______.
a. a soft solid.
b. a conducting solid.
c. a gas.
d. a brittle solid.
e. a liquid.

Answers

Answer:

d. a brittle solid.

Explanation:

Hello!

In this case, since cesium fluoride is widely known as an ionic compound due to the large electronegativity difference, it is possible to discard a. due to its crystalline structure, b. because conducting solids are metals, c. because ionic compounds are not likely to be gases and e. because even when it is soluble in water, the problem is not referring to an aqueous solution; therefore, the answer is d. a brittle solid.

Best regards!

What are the four types of human pathogens that
can cause infectious disease?

Answers

Answer:

Viruses, bacteria, fungi, and parasites.

Explanation:

hope this helps and is right :)

Examine the peptide. Peptide with three amino acid residues. The first residue contains a methyl group side chain. The second residue contains a hydrogen atom side chain. The third residue contains a hydroxymethyl group side chain. The amino group of the first side chain binds to the unshown remainder of the peptide. The carboxyl group of the third side chain binds to the unshown remainder of the peptide. Determine which amino acids are present in the peptide.

Answers

Answer:

The peptide is composed of Alanine, Glycine and Serine and is written in shorthand as: Ala-Gly-Ser.

Explanation:

Amino acids contain an α-carboxyl group, an α-amino group, and an R side chain which distinguishes one amino acid from another.

Peptides are chains of amino acids which are covalently bonded together through substituted amide linkages known as peptide bonds. The reaction occurs between an amino group of one amino acid and the carboxyl group of another amino acid with the removal of a water molecule.

A tripeptide is a peptide composed of three amino acids linked together by peptide bonds.

In the given peptide, the first residue contains a methyl group side chain. The second residue contains a hydrogen atom side chain. The third residue contains a hydroxymethyl group side chain.

The amino acid that contains a methyl group side chain is Alanine (Ala).

The amino acid that contains a hydrogen atom side chain is Glycine, Gly.

The amino acid that contains a hydroxymethyl group side chain is Serine, Ser.

Therefore, the peptide is composed of Alanine, Glycine and Serine and is written in shorthand as: Ala-Gly-Ser.

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