To create a buffer solution with a pH of 7.45 using NaClO and HClO, we need to calculate how many moles of HClO we need to combine with 0.25 moles of NaClO.
First, we need to find the concentration of NaClO in the solution:
0.25 moles NaClO / 1.00 L = 0.25 M NaClO
Next, we can use the Henderson-Hasselbalch equation:
pH = pKa + log([A-]/[HA])
where [A-] is the concentration of the conjugate base (NaClO) and [HA] is the concentration of the weak acid (HClO).
We know the pH is 7.45 and the pKa for HClO is 3.0 x 10^-8, so we can rearrange the equation to solve for [HA]:
[HA] = [A-] x 10^(pH - pKa)
[HA] = 0.25 M NaClO x 10^(7.45 - (-log(3.0 x 10^-8)))
[HA] = 1.56 x 10^-5 M HClO
Now we can calculate how many moles of HClO we need:
moles HClO = [HA] x volume
moles HClO = 1.56 x 10^-5 M x 1.00 L
moles HClO = 1.56 x 10^-5 mol
Therefore, we need 1.56 x 10^-5 moles of HClO to combine with 0.25 moles of NaClO to make a 1.00L buffer solution with pH = 7.45.
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How were clouds made?
Answer: Clouds form when the invisible water vapor in the air condenses into visible water droplets or ice crystals.
Explanation:
What is the conjugate base of H2PO4− ?A) HPO42-B) PO43- C) H3PO4D) H3O+ E) OH−
The conjugate base of H2PO4− is HPO42-. The answer is option A)
The conjugate base of an acid is the species formed after the acid donates a proton (H+). In other words, the conjugate base is the particle that remains after the acid has lost a proton.
In this case, H2PO4- is acid and it can donate one proton to form its conjugate base. When H2PO4- loses one proton, it becomes HPO42- which is its conjugate base.
Therefore, HPO42- is the answer.
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asymmetrical alkyne + Hâ‚‚ (2 mol equivalent) + Pd/C
The reaction of an asymmetrical alkyne with hydrogen gas (H2) in the presence of a palladium catalyst (Pd/C) typically results in the reduction of the alkyne to an alkene.
The reaction mechanism involves the formation of a π-complex between the alkyne and Pd/C, followed by syn-addition of two hydrogen atoms across the triple bond to give a cis-alkene intermediate.
This intermediate can undergo isomerization to form a trans-alkene, or it can undergo further hydrogenation to give a saturated alkane.
If the alkyne is asymmetrical, meaning that the two substituents on the triple bond are different, then the product will be a mixture of cis- and trans-alkenes.
The ratio of these two isomers will depend on the steric and electronic effects of the substituents and the reaction conditions.
Overall, the reaction of an asymmetrical alkyne with H2 and Pd/C is a useful method for the selective reduction of alkynes to alkenes, which are versatile building blocks in organic synthesis.
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_________ is exactly like SDS-PAGE, but with the addition of a reducing agent, like βmercaptoethanol, THAT WILL reduce disulfide bridges and result in a completely denatured protein.
Reducing SDS-PAGE is exactly like SDS-PAGE but with the addition of a reducing agent, like β-mercaptoethanol, that will reduce disulfide bridges and result in a completely denatured protein.
In this technique, proteins are separated based on their molecular weight. The process starts with denaturing the proteins using SDS, a detergent that binds to and unfolds the proteins.
The reducing agent, β-mercaptoethanol, is then added to the sample, which breaks the disulfide bridges holding the protein's structure together. This results in completely linear, denatured proteins. The proteins are then loaded into a polyacrylamide gel and subjected to an electric field.
As the proteins move through the gel, smaller proteins travel faster, creating a separation based on size. Reducing SDS-PAGE is useful for the accurate determination of molecular weights and analysis of protein structure.
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The reaction below can be identified as a _______________ reaction. 3H2 + N2 → 2NH3
An illustration of a combination reaction is the one that follows:
[tex]3H_2+N_2 - > 2NH_3[/tex].
What is Combination Reaction?When two or more compounds (reactants) combine to form a single substance (product), this is referred to as a combination reaction. This reaction also generates a large amount of energy in the form of heat in addition to the formation of new bonds and the products that arise.
Two reactants combine to produce one product in a combination reaction. Oxygen and halogens are very reactive, making them likely to mix with other elements to create new compounds. When two or more reactants combine to produce a single product, this is referred to as a combination reaction.
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why does a hydrophobic residue on the exterior of a protein require decreased entropy?
A hydrophobic residue on the exterior of a protein require decreased entropy so as to enable diffusion.
Diffusion is defined as the process of movement of molecules such as proteins which takes place under concentration gradient. It helps in movement of substances in and out from the cell.The molecules move from lower concentration region to a higher concentration region till the concentration becomes equal.
There are 2 main types of diffusion:
1) simple diffusion-process in which substances move through a semi-permeable membrane without the aid of transport proteins.
2) facilitated diffusion- It is a passive movement of molecules across cell membrane from higher concentration region to lower concentration.
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a sample of gas starts at 1.00 atm, 0.00 degrees celsius, and 30.0 ml. what is the volume if the temperature increases to 127 degrees celsius and the pressure decreases to 0.500 atm?
If the temperature increases to 127 degrees celsius and the pressure decreases to 0.500 atm, the final volume of the gas is approximately 66.1 mL
We will use the combined gas law, which is:
P[tex]_{1}[/tex] * V[tex]_{1}[/tex] / T[tex]_{1}[/tex] = P[tex]^{2}[/tex] * V[tex]^{2}[/tex] / T[tex]^{2}[/tex]
Where P[tex]_{1}[/tex] is the initial pressure (1.00 atm), V[tex]_{1}[/tex] is the initial volume (30.0 mL), T[tex]_{1}[/tex] is the initial temperature (0.00°C), P[tex]^{2}[/tex] is the final pressure (0.500 atm), V[tex]^{2}[/tex] is the final volume (which we want to find), and T[tex]^{2}[/tex] is the final temperature (127°C).
First, we need to convert the temperatures from Celsius to Kelvin:
T[tex]_{1}[/tex] = 0.00°C + 273.15 = 273.15 K
T[tex]^{2}[/tex] = 127°C + 273.15 = 400.15 K
Now, plug in the values into the combined gas law equation:
(1.00 atm) * (30.0 mL) / (273.15 K) = (0.500 atm) * V[tex]^{2}[/tex] / (400.15 K)
Next, solve for V[tex]^{2}[/tex]:
V[tex]^{2}[/tex] = (0.500 atm) * (30.0 mL) * (400.15 K) / (1.00 atm * 273.15 K)
V[tex]^{2}[/tex] ≈ 66.1 mL
So, the final volume of the gas is approximately 66.1 mL when the temperature increases to 127°C and the pressure decreases to 0.500 atm.
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methyl or 1Ë™ ether + HX (2 mol equivalent)
When methyl or 1˚ ether reacts with 2 equivalents of HX (hydrogen halide), the ether undergoes acid-catalyzed cleavage to form two products: an alkyl halide and an alcohol.
The reaction mechanism involves the protonation of the ether oxygen by HX, followed by nucleophilic attack by the halide ion on the carbon bearing the alkyl or aryl group. The overall reaction can be represented as follows:
R-O-R' + 2HX → R-X + R'-OH + HX
where R and R' represent alkyl or aryl groups.
For example, when methyl ether (CH3-O-CH3) reacts with two equivalents of HCl, it forms methyl chloride (CH3-Cl) and methanol (CH3-OH) according to the following reaction:
CH3-O-CH3 + 2HCl → CH3-Cl + CH3-OH + HCl
Similarly, when 1˚-butyl ether (C4H9-O-C4H9) reacts with two equivalents of HBr, it forms 1-bromobutane (C4H9-Br) and butanol (C4H9-OH) according to the following reaction:
C4H9-O-C4H9 + 2HBr → C4H9-Br + C4H9-OH + HBr
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How many different fin configurations are used for the B83?
The number of the different fin configurations that are used for the B83 is 10.
The B83 was the 12 feet long, that had the fins and the packed that is explosive force through the roughly 80 times greater as compared to that of the Hiroshima bomb. The job of this was to obliterate the hardened military sites and the command bunkers, that is including the Moscow's.
The Blast bombs is the light cases and the poorer penetration. The Penetration bombs is the cases that is hard enough to the penetrate concrete and the armor plating. The B83 pales as compared to others the most powerful bomb that is ever made.
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What are the relationships between Ka, Kb, Kw, pKa , pKb, and pKw
The relationships between these values can be described by the following equations:
Ka x Kb = Kw
pKa + pKb = pKw
Ka, Kb, and Kw are all equilibrium constants that relate to the strength of acids and bases in solution.
Ka is the acid dissociation constant, which describes the extent to which an acid donates a proton (H+) in solution. It is calculated by dividing the concentration of the products of the dissociation reaction by the concentration of the acid.
Kb is the base dissociation constant, which describes the extent to which a base accepts a proton (H+) in solution. It is calculated by dividing the concentration of the products of the dissociation reaction by the concentration of the base.
Kw is the ion product constant for water, which describes the extent to which water dissociates into H+ and OH- ions in solution. It is equal to the product of the concentrations of H+ and OH- ions in solution.
pKa and pKb are logarithmic measures of the acid and base dissociation constants, respectively. They are calculated by taking the negative logarithm of the respective equilibrium constant values.
pKw is the negative logarithm of Kw, and is equal to 14 at 25°C.
The relationships between these values can be described by the following equations: Ka x Kb = Kw
pKa + pKb = pKw
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Give two differences between the physical properties of the elements in Group 1 and those of the transition elements. [2 marks
Due to their stronger metallic bonding and more compact atomic structure, the transition elements have higher melting and boiling temperatures and are often denser than the alkali metals.
What are group one metals' two physical characteristics?Elements from Group 1 have similar properties. All of them are supple silver metals. These metals are extremely reactive and have low melting temperatures due to their low ionisation energy. As you descend the chart, this family becomes more reactive.
What are the transitional elements?The d orbitals of transitional elements are only partially filled. A transition element is defined by IUPAC as an element that may form stable cations and has an electron d subshell that is only partly filled.
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true or false Thermal energy flows into the reaction and out of the surroundings in an endothermic reaction.
True. In an endothermic reaction, thermal energy is absorbed from the surroundings and flows into the reaction, making the surroundings cooler.
How to determine the thermal energy of endothermic reaction?The thermal energy flows into the reaction and out of the surroundings in an endothermic reaction. In an endothermic reaction, energy is absorbed from the surroundings, causing the temperature of the surroundings to decrease. This energy transfer results in an increase in the internal energy of the system undergoing the reaction. This results in an increase in the internal energy of the system, which is why endothermic reactions often feel cold.
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the following structure is best represented as a. furanose with an alpha hydroxy group. b. pyranose with an alpha hydroxy group. c. furanose with a beta hydroxy group. d. pyranose with a beta hydroxy group.
The best representation of the given structure is a furanose with an alpha hydroxy group.
Furanose is a type of carbohydrate ring structure and consists of four carbon atoms with one oxygen atom in the center. The alpha hydroxy group is a functional group that consists of a carbon atom with two hydroxyl groups on either side. The presence of this group in the furanose ring structure changes the properties of the molecule, such as its reactivity and solubility.
The orientation of the hydroxy group is also important, and in this case, it is positioned at the alpha position, which means it is directly attached to one of the four carbon atoms of the ring. This configuration makes the molecule more reactive, and it can undergo various chemical reactions more easily than if it had a beta hydroxy group.
Pyranose is another type of carbohydrate ring structure, but it is made up of six carbon atoms instead of four and the orientation of the hydroxy group is different, so it is not the best representation of the given structure.
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63) Give the name for PI3.A) phosphorus triiodideB) potassium triiodideC) phosphorus(III) iodideD) phosphorus(II) iodideE) phosphorus iodide
The name for PI3 is phosphorus triiodide. The correct option is A.
PI3 is a covalent compound composed of phosphorus and iodine, with the molecular formula PI3. The compound is a dark red solid with a pungent odor and is highly reactive, decomposing rapidly in water and air.
The name "phosphorus triiodide" follows the standard naming convention for covalent compounds, where the prefix "tri-" indicates that the compound contains three iodine atoms bonded to one phosphorus atom.
The prefix "phosphorus" indicates the presence of a phosphorus atom, while the suffix "-ide" indicates that iodine is in its anionic form.
It is important to note that the other options listed (potassium triiodide, phosphorus(III) iodide, phosphorus(II) iodide, and phosphorus iodide) are all valid compounds with different chemical formulas and properties.
The correct name for each of these compounds is as follows:
B) Potassium triiodide is KI3
C) Phosphorus(III) iodide is PI3
D) Phosphorus(II) iodide is not a valid compound.
E) Phosphorus iodide is not a specific compound and can refer to several different phosphorus-iodine compounds with varying formulas and properties.
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what does protonation of a functional group do to it (like alcohol or an oxygen)
Protonation of a functional group, like an alcohol or an oxygen, generally does the following:
1. Increases the acidity of the functional group: Protonation adds a hydrogen ion (H+) to the functional group, which increases its acidity by creating a positive charge on the molecule.
2. Makes the functional group more reactive: The addition of a hydrogen ion increases the reactivity of the functional group, making it more likely to participate in chemical reactions.
3. Changes the polarity of the functional group: Protonation affects the distribution of electron density within the functional group, altering its polarity and potentially affecting its solubility and other properties.
In summary, protonation of a functional group like alcohol or oxygen increases its acidity, reactivity, and changes its polarity.
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47) How many moles of calcium chloride are theoretically produced for the following reaction given we have 2.6 moles of HCl and 1.4 moles of Ca(OH)2?
Reaction: 2HCl + Ca(OH)2 → 2H2O + CaCl2
A) 0.7
B) 1.0
C) 1.4
D) 1.3
E) not enough information
1.4 moles. of calcium chloride are theoretically produced for the following reaction given we have 2.6 moles of HCl and 1.4 moles of [tex]Ca(OH)$_2$[/tex].option (c)
To determine the number of moles of calcium chloride [tex]CaCl$_2$[/tex] produced in the reaction, we first need to identify the limiting reactant, which we determined in the previous question to be [tex]Ca(OH)$_2$[/tex].
Using the stoichiometry of the balanced chemical equation, we can see that for every 1 mole of [tex]Ca(OH)$_2$[/tex], 1 mole of [tex]CaCl$_2$[/tex]is produced. Therefore, if 1.4 moles of [tex]Ca(OH)$_2$[/tex] is used up, then 1.4 moles of [tex]CaCl$_2$[/tex] would be produced.
Therefore, the answer is C) 1.4 moles.
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To get salt out of a solution (separating salt from water) we could try
Select one:
a. evaporating the water so the salt is left behind
b. drinking the water
c. melting it
d. using the solute to redissolve it
e. using a magnet
To get salt out of a solution (separating salt from water), you could try:
a. evaporating the water so the salt is left behind
This is the correct method because as the water evaporates, the salt, which does not evaporate, will be left behind as solid crystals. The other options (b, c, d, and e) are not effective methods for separating salt from water.
In order to turn seawater into freshwater you have to remove the dissolved salt in seawater. That may seem as easy as just boiling some seawater in a pan, capturing the steam and condensing it back into water (distillation).
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Aluminum chloride is a sold at 25'C. Is the boiling point of methan higher than 25'C, or is it lower than 25'C. How can you tell?
Methane, being a gas, would have a lower boiling point than aluminum chloride, and is likely to be in a gaseous state at room temperature.
Methane (CH4) is a simple hydrocarbon gas that is typically known to have a boiling point lower than 25°C at standard atmospheric pressure (1 atm).
Aluminum chloride (AlCl3), on the other hand, is a solid compound at 25°C. It has a high melting and boiling point, and it is typically known to be a solid at room temperature (25°C) and atmospheric pressure.
Based on these properties, we can infer that the boiling point of methane (CH4) is lower than 25°C. This is because aluminum chloride (AlCl3), which is a solid at 25°C, would not be in a liquid state at or below 25°C, and therefore cannot have a boiling point higher than 25°C.
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two step strategy for percent composition from experimental data
Two step strategy to determine percent composition from experimental data are to calculate the moles of each element and Calculate the percent composition.
To determine the percent composition from experimental data, we have to follow this two-step strategy:
1. Calculate the moles of each element: Divide the mass of each element obtained from the experimental data by its respective atomic weight (found on the periodic table). This will give you the moles of each element in the sample.
2. Calculate the percent composition: Divide the moles of each element by the total moles of all elements in the sample, then multiply the result by 100 to obtain the percentage. This will give you the percent composition of each element in the compound.
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What practice bomb is used to simulate the B61?
The practice bomb is used to simulate the B61 is the thermonuclear gravity bomb.
The B61 nuclear bomb is the bomb that is primary the thermonuclear gravity bomb in the United States that is enduring the stockpile the end of the Cold War. The B61 nuclear bomb is the low to the intermediate-yield strategic or the tactical nuclear weapon that is featuring the two-stage radiation that implosion in the design.
The B61 nuclear bomb is detonate the beneath of the Earth's surface, that will increasing the destructiveness in against the underground targets and to the equivalent of the surface that burst the weapon and yield of the 1,250 kilotons.
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A girl who weighs 36kg(about 80lbs) is about to go down a slide that is 1. 5m tall. How much energy is being used
The girl who weighs 36 kg is about to go down the slide that is the 1.5 m tall. The energy is being used is 529.2 kJ.
The weight of the girl = 36 kg
The height of the tall = 1.5 m
The expression for the energy is as :
Energy = m g h
Where,
The mass, m = 36 kg
The acceleration to the gravity, g = 9.8 m/s²
The height, h = 1.5 m
The energy = 36 kg × 9.8 m/s² × 1.5 m
The energy = 529.2 kJ
The energy used is 529.2 kJ, when the girl who weight is 36kg that is 80lbs and will about to go down the slide that is the 1. 5m tall.
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A buffer is prepared containing 0.800 molar acetic acid and 1.00 molar sodium acetate. What is its pH?
The pH of the buffer containing 0.800 molar acetic acid and 1.00 molar sodium acetate is approximately 4.84.
To calculate the pH of a buffer containing 0.800 M acetic acid and 1.00 M sodium acetate, you can use the Henderson-Hasselbalch equation:
pH = pKa + log10([A-]/[HA])
Here, pKa is the negative logarithm of the acid dissociation constant (Ka) for acetic acid, [A-] is the concentration of the conjugate base (acetate ion from sodium acetate), and [HA] is the concentration of the weak acid (acetic acid).
The pKa of acetic acid is approximately 4.74. Plugging the concentrations into the equation:
pH = 4.74 + log10(1.00 M / 0.800 M)
pH ≈ 4.74 + 0.1
pH ≈ 4.84
So, the pH of the buffer solution is approximately 4.84.
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the boiling point of liquid hydrogen is 20.3 k at atm- 10.3 thermal expansion of solids and liquids spheric pressure. what is this temperature on (a) the celsius scale and (b) the fahrenheit scale?
The boiling point of liquid hydrogen is (a) -252.85°C on the Celsius scale and (b) -423.13°F on the Fahrenheit scale.
To convert the boiling point of liquid hydrogen, which is 20.3 K, to (a) the Celsius scale and (b) the Fahrenheit scale, follow these steps:
(a) Celsius scale:
1. Subtract 273.15 from the Kelvin temperature.
2. The result is the temperature in Celsius.
20.3 K - 273.15 = -252.85°C
(b) Fahrenheit scale:
1. Convert the Celsius temperature to Fahrenheit using the formula: F = (C × 9/5) + 32
2. The result is the temperature in Fahrenheit.
-252.85°C × 9/5 + 32 = -423.13°F
In conclusion, the boiling point of liquid hydrogen is (a) -252.85°C on the Celsius scale and (b) -423.13°F on the Fahrenheit scale.
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The molar solubility of CuI is 2.26 × 10⁻⁶ M in pure water. Calculate the Ksp for CuI.A) 5.11 × 10⁻¹²B) 1.02 × 10⁻¹¹C) 4.52 × 10⁻⁶D) 4.62 × 10⁻¹⁷E) 1.50 × 10⁻³
The correct option is A, the Ksp for Cul is 5.11 × 10⁻¹².
CuI (s) ⇌ Cu⁺ (aq) + I⁻ (aq)
Ksp = [Cu⁺][I⁻]
Since CuI dissolves completely to form one Cu⁺ ion and one I⁻ ion, the concentration of Cu⁺ and I⁻ ions is the same as the molar solubility of CuI.
Therefore, Ksp = (2.26 × 10⁻⁶)² = 5.11 × 10⁻¹²
Ksp stands for solubility product constant and is a measure of the extent to which a solute dissolves in a solvent. It is defined as the product of the concentrations of the ions in a saturated solution of a sparingly soluble salt at a given temperature. In other words, it represents the equilibrium constant for the dissolution of a solid substance in a solvent.
Ksp is an important concept in chemistry because it helps to predict the solubility of a substance and its behavior in solution. For example, if the Ksp value for a substance is high, it means that the substance is highly soluble and will dissolve easily in a solvent. Conversely, if the Ksp value is low, the substance will be less soluble and may form a precipitate. Calculating Ksp requires knowledge of the balanced equation for the dissolution of the substance, as well as the concentrations of the ions in solution.
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When calcium ions (Ca2+) are electrolytically reduced to calcium metal, what is the relationship between the moles of electrons transferred and the moles of Ca (s) produced?
When calcium ions (Ca2+) are electrolytically reduced to calcium metal, each calcium ion gains two electrons to form one mole of calcium metal (Ca(s)). Therefore, the relationship between the moles of electrons transferred and the moles of Ca (s) produced is a 2:1 ratio.
What happens during an electrolytic reaction?When calcium ions (Ca2+) are electrolytically reduced to calcium metal, the relationship between the moles of electrons transferred and the moles of Ca(s) produced is that 2 moles of electrons are required to produce 1 mole of calcium metal. This is because the reduction of Ca2+ to Ca(s) involves a 2-electron transfer, as represented by the following half-reaction:
Ca2+ + 2e- → Ca(s)
In this reaction, each calcium ion gains 2 electrons to become a calcium atom in the solid form. Therefore, the ratio of moles of electrons transferred to moles of Ca(s) produced is 2:1.
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46) What is the excess reactant for the following reaction given we have 2.6 moles of HCl and 1.4 moles of Ca(OH)2?
Reaction: 2HCl + Ca(OH)2 → 2H2O + CaCl2
A) Ca(OH)2
B) HCl
C) H2O
D) CaCl2
E) not enough information
Since we have 1.4 moles of Ca(OH)2, which is greater than the calculated amount needed, Ca(OH)2 is in excess and the answer is A) Ca(OH)2.
How to determine the excess reagent?To determine the excess reactant for the given reaction, we will use the balanced chemical equation and the provided moles of reactants. The balanced equation is:
2HCl + Ca(OH)2 → 2H2O + CaCl2
We have 2.6 moles of HCl and 1.4 moles of Ca(OH)2. To find the limiting reactant, we'll compare the mole ratios of the reactants:
Mole ratio of HCl to Ca(OH)2 = 2:1
Now, divide the given moles by the coefficients in the balanced equation:
HCl: 2.6 moles / 2 = 1.3
Ca(OH)2: 1.4 moles / 1 = 1.4
Since 1.3 is smaller than 1.4, HCl is the limiting reactant. Therefore, Ca(OH)2 is the excess reactant.
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a ground-state h atom absorbs a photon of wavelength 91.53 nm. what higher energy level did the electron reach?
The electron reached the higher energy level of 6 after absorbing the photon of wavelength 91.53 nm.
A ground-state hydrogen atom absorbs a photon of wavelength 91.53 nm. Using the Balmer formula and Rydberg constant, we can determine the higher energy level the electron reached.
The Balmer formula is:
1/λ = R_H * (1/n1² - 1/n2²)
where λ is the wavelength (91.53 nm), R_H is the Rydberg constant for hydrogen (approximately 1.097 x 10^7 m^-1), n1 and n2 are the principal quantum numbers of the initial and final energy levels.
In the ground-state, n1 = 1, as the electron is in the first energy level. Substituting the given values, we get:
1/91.53 x 10^-9 = 1.097 x 10^7 * (1/1² - 1/n2²)
Solving for n2, we find that n2 ≈ 6.
So, the electron reached the higher energy level of 6 after absorbing the photon of wavelength 91.53 nm.
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an acid and a base will neutralize each other to form a salt and water. in these neutralization reactions, the acid and base are called
In chemistry, when an acid and a base react with each other, they neutralize to form a salt and water. This neutralization reaction occurs when the hydrogen ions (H+) in the acid react with the hydroxide ions (OH-) in the base.
During the reaction, the hydrogen and hydroxide ions combine to form water, while the remaining ions combine to form a salt. The acid and base are referred to as reactants in this reaction, as they are the starting materials that react with each other to produce the salt and water.
The products of the reaction are the salt and water that are formed. This neutralization reaction is an example of an ionic reaction, as it involves the transfer of electrons between the two reactants. The reaction is also exothermic, meaning that it releases energy in the form of heat.
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sotactic poly(methyl methacrylate) has a much lower t g than the corresponding syndiotactic polymer. explain why isotactic pmma has a lower t g.
Isotactic PMMA has a lower Tg because it is strongly influenced by its stereochemical structure and the degree of order and packing of its polymer chains.
The glass transition temperature (Tg) is the temperature at which a polymer changes from a glassy state to a more rubbery state.
The Tg is influenced by the arrangement of the monomers within the polymer chains, which is referred to as tacticity.
Isotactic PMMA has a regular arrangement of the methyl groups on the same side of the polymer chain, while syndiotactic PMMA has alternating positions of the methyl groups along the chain.
The isotactic arrangement allows for closer packing of the polymer chains due to the uniformity of the side groups.
This results in stronger van der Waals forces between the chains, which allows for more efficient packing of the polymer chains.
In contrast, syndiotactic PMMA's alternating arrangement of methyl groups leads to a more irregular packing of the polymer chains.
This reduces the strength of the van der Waals forces between the chains, making the packing less efficient.
As a result, isotactic PMMA has a lower Tg than syndiotactic PMMA due to the stronger intermolecular forces and more efficient packing of the polymer chains.
This enables isotactic PMMA to become more flexible and rubbery at lower temperatures compared to its syndiotactic counterpart.
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Calculate the % composition of these compounds:A. Ethane (C2H6)B. Sodium hydrogen sulfate (NaHSO4)
The percentage composition of ethane is 39.99% carbon
60.01% hydrogen and that of sodium hydrogen sulfate is 19.15% sodium 0.84% hydrogen 26.71% sulfur 53.30% oxygen
A. Ethane (C2H6)
To calculate the percent composition of ethane, we need to determine the molar mass of the compound, which is the sum of the atomic masses of all the atoms in the molecule.
Molar mass of ethane = (2 × molar mass of carbon) + (6 × molar mass of hydrogen)
= (2 × 12.011 g/mol) + (6 × 1.008 g/mol)
= 30.07 g/mol
Now we can calculate the percent composition of each element in ethane:
% composition of carbon = (2 × molar mass of carbon ÷ molar mass of ethane) × 100%
= (2 × 12.011 g/mol ÷ 30.07 g/mol) × 100%
= 39.99%
% composition of hydrogen = (6 × molar mass of hydrogen ÷ molar mass of ethane) × 100%
= (6 × 1.008 g/mol ÷ 30.07 g/mol) × 100%
= 60.01%
Therefore, the percent composition of ethane is:
39.99% carbon
60.01% hydrogen
B. Sodium hydrogen sulfate (NaHSO4)
To calculate the percent composition of sodium hydrogen sulfate, we need to determine the molar mass of the compound.
Molar mass of NaHSO4 = molar mass of Na + molar mass of H + molar mass of S + 4 × molar mass of O
= 22.99 g/mol + 1.008 g/mol + 32.06 g/mol + 4 × 16.00 g/mol
= 120.06 g/mol
Now we can calculate the percent composition of each element in sodium hydrogen sulfate:
% composition of sodium = (molar mass of Na ÷ molar mass of NaHSO4) × 100%
= (22.99 g/mol ÷ 120.06 g/mol) × 100%
= 19.15%
% composition of hydrogen = (molar mass of H ÷ molar mass of NaHSO4) × 100%
= (1.008 g/mol ÷ 120.06 g/mol) × 100%
= 0.84%
% composition of sulfur = (molar mass of S ÷ molar mass of NaHSO4) × 100%
= (32.06 g/mol ÷ 120.06 g/mol) × 100%
= 26.71%
% composition of oxygen = (4 × molar mass of O ÷ molar mass of NaHSO4) × 100%
= (4 × 16.00 g/mol ÷ 120.06 g/mol) × 100%
= 53.30%
Therefore, the percent composition of sodium hydrogen sulfate is:
19.15% sodium
0.84% hydrogen
26.71% sulfur
53.30% oxygen
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