how can we calculate the pI of a negatively charged (acidic) amino acid?

Prevention and maintenance of painful joints involves a variety of approaches, depending on the specific joint and the underlying cause of the pain. For example, arm slings, arm troughs, and playboards can be used to support and stabilize painful shoulders, elbows, wrists, and hands, while immobilization may be necessary for healing or protection of tissues.

In some cases, providing stability or restricting unwanted movement/motion can be beneficial, such as in the case of preventing contractures or normalizing tone.
To restore mobility to joints, a variety of techniques may be used, including physical therapy, stretching exercises, and joint mobilization. It's important to work with a healthcare professional to develop a personalized treatment plan that addresses your specific needs and goals. With proper care and management, it is often possible to improve mobility and reduce pain in painful joints.

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The equation that would be used to calculate the mass of calcium deposited in 30.0 seconds using a current of 2.0 A is Faraday's law of electrolysis.

The law states that the amount of substance produced at an electrode during electrolysis is directly proportional to the amount of electrical charge passed through the electrode. The equation for the law is:

Amount of substance = (Electric current x Time x Atomic mass) / (Number of electrons x Faraday's constant)

Using the values given in the question, the atomic mass of calcium is 40.08 g/mol, the number of electrons involved in the reduction reaction is 2, and the Faraday's constant is 96,485 C/mol. Plugging these values into the equation, we get:

Amount of substance = (2.0 A x 30.0 s x 40.08 g/mol) / (2 x 96,485 C/mol)
= 0.0195 g

Therefore, the mass of calcium deposited on the electrode in 30.0 seconds using a current of 2.0 A is 0.0195 g.

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The Gibbs free energy for the reaction 2A + B → 2C is -401. The answer is a.

To find ΔG for the given reaction, we can use the Gibbs-Helmholtz equation:

ΔG_rxn = ΔH_rxn - TΔS_rxn

First, we need to find ΔH_rxn and ΔS_rxn for the reaction. We can do this by manipulating the given equations:

A → B: ΔG₁ = 128

C → 2B: ΔG₂ = 455

A → C: ΔG₃ = -182

Adding the equations for ΔG₁ and ΔG₂, we get:

C → A + B: ΔG = ΔG₁ + ΔG₂ = 583

Subtracting the equation for ΔG₃ from ΔG, we get:

2A + B → 2C: ΔG_rxn = ΔG - ΔG₃ = 401

Therefore, the ΔG for the reaction 2A + B → 2C is -401 kJ/mol. The answer is (a).

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The correct answer is C) chlorine monoxide.The naming of binary compounds containing non-metals follows a specific convention.

The first element in the formula is named first, using its elemental name. The second element is named second, changing the ending of its elemental name to "-ide."

In this case, ClO is a binary compound consisting of the elements chlorine (Cl) and oxygen (O). Since chlorine is listed first, it is named first. The prefix "mono-" is used to indicate that there is only one atom of each element in the compound.

The second element, oxygen, is named second and its ending is changed to "-ide." Therefore, the correct name for ClO is chlorine monoxide.

A) Chlorite is the name of a polyatomic ion, which contains chlorine and oxygen, but has a different chemical formula and charge.

B) Hypochlorite is also the name of a polyatomic ion that contains chlorine and oxygen, but again, it has a different chemical formula and charge.

D) Chlorine (II) oxide is not a correct name for ClO, as it implies that chlorine has a +2 oxidation state, which is not the case in this compound.

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Assuming that protective groups did not alter the amino acids, dehydration causes peptide bonds to bind together, producing water H2O as a byproduct. The mass of H₂O is 18.

The 9-fluorenyl methoxy carbonyl  groups, employed as part of the  respectively, methods, are the most popular -amino-protecting radicals for solid-phase peptide synthesis (SPPS).

By creating a Boc derivative, the amino group is shielded from damage. Dicyclohexylcarbodiimide (DCCI) is used to form an amide link between each of these protected amino acids. Trifluoroacetic acid is used to hydrolyze the Boc group in order to continue the peptide's extension.

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The number of moles of CO₂ that are produced from the combustion of 6. 40 mol C₃H₈ is 19.2 moles.

Generally Combustion reactions is defined as the reactions that occur as oxygen reacts with another element and emits heat and light.

The balanced chemical reaction is given as:

C₃H₈ + 4 O₂ ➞ 3 CO₂ + 5 H₂O

From the reaction it is clear that 1 mole of propane produces 3 moles of carbon dioxide.

So, 6.40 moles of propane will produce carbon dioxide = 3 × 6.40 moles = 19.2 moles of carbon dioxide.

Hence, the number of moles of CO₂ that are produced from the combustion of 6. 40 mol C₃H₈ is 19.2 moles.

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The percent ionization of a 1.45 M aqueous acetic acid solution is approximately 1.19%.

Assuming that x is the extent of dissociation, the equilibrium concentrations of acetic acid, acetate ion, and hydrogen ion can be expressed as follows:

[CH3COOH] = (1.45 - x) M

[C2H3O2-] = x M

[H+] = x M

Ka = [H+] [C2H3O2-] / [CH3COOH]

[tex]1.8 * 10^-5 = x^2 / (1.45 - x)[/tex]

Since the extent of dissociation (x) is expected to be small compared to the initial concentration, we can approximate (1.45 - x) to 1.45 and solve for x using the quadratic formula:

[tex]x = [1.45 +/- sqrt(1.45^2 + 4 * 1.8 x 10^-5 * 1.45)] / 2 \\x = 0.0172 M (approx)[/tex]

Percent ionization:

% ionization = 1.19 %

Therefore, the percent ionization of a 1.45 M aqueous acetic acid solution is approximately 1.19%.

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--The Complete Question is , What is the percent ionization of a 1.45 M aqueous acetic acid solution?--

NH₃/NH₄⁺ are a Bronsted-Lowry conjugate acid-base pair. The answer is a.

In a Bronsted-Lowry acid-base reaction, an acid donates a proton (H⁺) to a base, which accepts the proton. The species that donates the proton becomes the conjugate base, and the species that accepts the proton becomes the conjugate acid.

In option a, NH₃ is a base because it can accept a proton to form NH₄⁺, which is an acid because it can donate a proton to reform NH₃. Therefore, NH₃ and NH₄⁺ form a conjugate acid-base pair.

Option b shows a self-conjugate acid-base pair, where H₃O⁺ is an acid and can donate a proton to form H₂O, which is a base. However, H₂O can also donate a proton to form OH⁻, making it an acid. Therefore, H₃O⁺, H₂O, and OH⁻ are all part of the same conjugate acid-base pair.

Option c does not show a conjugate acid-base pair as both HCl and HBr are acids, and they cannot form each other by donating or accepting a proton.

Option d also does not show a conjugate acid-base pair because ClO₄⁻ and ClO₃⁻ are both oxyanions and cannot act as acids or bases in this context.

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The observation we would expect to upon the reaction of hydrochloric acid with sodium bicarbonate is bubbles and heat.

When hydrochloric acid reacts with sodium bicarbonate, we would expect to observe the following:

Bubbles: Sodium bicarbonate and hydrochloric acid combine to form carbon dioxide gas, which is visible as bubbles in the solution.

Heat: Exothermic meaning that heat is released during the process. As a result, a minor rise in temperature is to be expected.

No precipitation: As a result of this reaction, sodium chloride, carbon dioxide, and water are produced. Since none of these are insoluble in water, there shouldn't be any precipitation.

Therefore, the correct options are bubbles and heat.

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The reaction of an asymmetrical alkyne with one equivalent of a halogen, X₂ , typically results in the addition of the halogen to the alkyne to form a dihaloalkene product. correct option is A) dihaloalkene product.

The regioselectivity of the reaction depends on the electronic nature of the alkyne and the halogen.

If the alkyne is electron-rich, the halogen is likely to add to the less substituted carbon atom (Markovnikov addition). Conversely, if the alkyne is electron-poor, the halogen is likely to add to the more substituted carbon atom (anti-Markovnikov addition).

For example, the reaction of propyne (an asymmetrical alkyne) with bromine (Br₂) can give two possible products: 1,2-dibromopropene (Markovnikov addition) or 1,1-dibromopropene (anti-Markovnikov addition), depending on the reaction conditions and the substituents on the alkyne.

Overall, the addition of X₂ to an asymmetrical alkyne can lead to a mixture of products, depending on the regioselectivity of the reaction.

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the complete question is :

asymmetrical alkyne + X₂ (1mol equivalent) →

What is the product formed when an asymmetrical alkyne is treated with one mole equivalent of X₂?

A) dihaloalkene product

B) halogens

C) hexanes

D) haloaklanes

The mass of 2450 mL of ethanol with a specific gravity of 0.810 is 1984.5 grams.

The equation to calculate the mass (in grams) of a substance using its specific gravity (SG) and volume (in milliliters) in the SI system is:

Grams = milliliters × SG

For example, let's say you have 2450 mL of ethanol with a specific gravity of 0.810. To calculate the mass in grams, you would use the following equation:

Grams = 2450 mL × 0.810

Simplifying the equation, you get:

Grams = 1984.5 g

Therefore, the mass of 2450 mL of ethanol with a specific gravity of 0.810 is 1984.5 grams.

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We need to add 1.45 x 10^6 moles of NaF to 1.00 L of the solution to prepare a buffer solution with a pH of 3.26.

To prepare a solution with a pH of 3.26 using HF and NaF, we need to use the Henderson-Hasselbalch equation:

pH = pKa + log([F-]/[HF])

where pKa is the acid dissociation constant of HF, [F-] is the concentration of the conjugate base NaF, and [HF] is the concentration of the acid HF.

We can rearrange this equation to solve for [F-]/[HF]:

[F-]/[HF] = antilog(pH - pKa)

Substituting the given values, we get:

[F-]/[HF] = antilog(3.26 - (-log(7.2 x 10^-4))) = antilog(3.26 + 3.14) = antilog(6.40) = 2.51 x 10^6

Therefore, the required ratio of [F-] to [HF] is 2.51 x 10^6. If we add 0.577 moles of HF to 1.00 L of solution, the concentration of HF will be:

[HF] = moles of HF / volume of solution = 0.577 mol / 1.00 L = 0.577 M

To calculate the moles of NaF needed, we can use the desired ratio of [F-] to [HF] and the known concentration of HF:

[F-]/[HF] = [NaF] / [HF]

2.51 x 10^6 = [NaF] / 0.577 M

[NaF] = 2.51 x 10^6 x 0.577 M = 1.45 x 10^6 mol/L

To prepare a 1.00 L solution with this concentration of NaF, we need to add:

moles of NaF = [NaF] x volume of solution = 1.45 x 10^6 mol/L x 1.00 L = 1.45 x 10^6 mol

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The other factors can also influence the rate and extent of dissolution.

When solutes have a slightly negative change in free energy, they are likely to dissolve in a solvent.

Free energy is a measure of the amount of energy available to do work in a system. In the case of a solute dissolving in a solvent, the change in free energy is the difference in free energy between the solute and solvent before and after they come into contact.

If the overall change in free energy is negative, meaning the system has more energy available to do work after the solute dissolves in the solvent, then the solute is likely to dissolve.

In general, the solubility of a solute depends on several factors, including the strength of the intermolecular forces between the solute and solvent molecules, the temperature, and the pressure. When solutes have a slightly negative change in free energy.

it suggests that the intermolecular forces between the solute and solvent are favorable, making it easier for the solute to dissolve in the solvent.

It's important to note that a slightly negative change in free energy does not guarantee that the solute will dissolve completely or quickly.

The rate and extent of dissolution can depend on factors such as the solute concentration, agitation of the solution, and the presence of other solutes or impurities that may interfere with dissolution.

In summary, solutes with a slightly negative change in free energy are likely to dissolve in a solvent due to favorable intermolecular forces between the solute and solvent molecules.

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173 g of HF must react in order to produce 345 kJ of energy. Option (5)

The first step is to calculate the amount of energy produced by the reaction when 1 mole of HF reacts. From the balanced chemical equation, we can see that the reaction produces 4 moles of HF for every -184 kJ of energy released.

Therefore, the amount of energy released when 1 mole of HF reacts is:

[tex]\frac{-184,kJ}{4,mol,HF} = -46,kJ/mol,HF[/tex]

Next, we can use this value to calculate the amount of HF needed to produce 345 kJ of energy:

[tex]\text{345 kJ} \times \frac{1,mol,HF}{-46,kJ} \times \frac{20.01,g,HF}{1,mol,HF} = 173,g,HF[/tex]

Therefore, 173 g of HF must react in order to produce 345 kJ of energy.

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Full Question: According to the following thermochemical equation, what mass of HF (in g) must react in order to produce 345 kJ of energy? Assume excess SiO2.

SiO2(s) + 4 HF(g) → SiF4(g) + 2 H2O(l) ΔH°rxn = -184 kJ

Ignoring stereochemistry, 6 different tripeptides can be formed.

Ignoring stereochemistry, it is noted that there are 6 different tripeptides that can be formed using the same 3 amino acids. Therefore, the correct option is (c) 6.

To explain this further, we can consider the fact that there are 3 amino acid residues to be arranged in a linear sequence to form a tripeptide. Since we are ignoring stereochemistry, we can assume that each of the 3 amino acids is distinct from one another, and therefore can be arranged in 3! = 6 different ways. These 6 different arrangements will result in 6 different tripeptides containing the same 3 amino acids.

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The volume of 0.3000 M HCl required to contain 1.5000 g of HCl is b. 139 ml.

To calculate the volume of 0.3000 M HCl required to contain 1.5000 g of HCl.

we need to use the equation:

n = m/MW

Where n is the number of moles, m is the mass in grams, and MW is the molecular weight of HCl.

First, we need to calculate the number of moles of HCl in 1.5000 g of HCl:

n = 1.5000 g / 36.0 g/mol = 0.04167 mol

Next, we can use the equation:

C = n/V

Where C is the concentration in M, n is the number of moles, and V is the volume in liters.

Rearranging the equation, we get:

V = n/C

Plugging in the values, we get:

V = 0.04167 mol / 0.3000 mol/L = 0.1389 L

To convert liters to milliliters, we multiply by 1000:

V = 0.1389 L x 1000 mL/L = 138.9 mL

Therefore, the volume of 0.3000 M HCl required to contain 1.5000 g of HCl is 138.9 mL.

In summary, we used the mass of HCl and its molecular weight to calculate the number of moles. Then, we used the concentration of the HCl solution and the number of moles to calculate the volume of the solution required to contain the given mass of HCl. Therefore, the correct answer is option b.

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The balanced half-reaction is:  NO2- + 4H+ + 2e- → NH4+. To balance the half-reaction of NO2- → NH4+, we first need to determine the missing coefficients. On the reactant side, we have one nitrogen atom and two oxygen atoms. On the product side, we have one nitrogen atom and four hydrogen atoms.

To balance the number of nitrogen atoms, we need a coefficient of 1 on both sides. To balance the number of hydrogen atoms, we need a coefficient of 4 on the product side. Finally, to balance the number of oxygen atoms, we need a coefficient of 2 on the reactant side.

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Hydration is a specific example of the phenomenon known generally as a. solvation

The act of hydrating involves combining or dissolving an object in water. It is a particular instance of the more general phenomena known as solvation, which is the process by which solvent molecules surround and scatter a solute to create a homogeneous solution. However, hydration explicitly refers to solvation with water as the solvent.

Solvation may also happen with solvents other than water. Solvation is the process through which a solute and solvent interact to stabilise a solute species. Due to its impact on the solubility, reactivity, and behaviour of compounds in solution, solvation is a crucial mechanism in many chemical and biological processes.

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A higher Km indicates low affinity of the enzymes for its substrate.

The rate of reaction involving an enzyme is greatly influenced by temperature, pH, concentration of the substrate, and a number of other factors.

The substrate concentration needed for half-maximum velocity (1/2 Vmax) is called the Km value (Michaelis constant) and is expressed in units of substrate concentration (moles per liter or M).

Km may be considered an approximate measure of affinity of an enzyme for its substrate: the lower the Km, the higher is the affinity.

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The concentration of sodium formate in the buffer solution is 2.93 x [tex]10^{-3}[/tex] M.

To find the concentration of sodium formate in the buffer solution, we need to use the Henderson-Hasselbalch equation:

pH = pKa + log([NaCOOH] / [HCOOH])

Substituting the given values:

4.358 = 3.77 + log([NaCOOH] / 0.00750)

0.588 = log([NaCOOH] / 0.00750)

[NaCOOH] / 0.00750 = 3.91 x [tex]10^{-1}[/tex]

[NaCOOH] = 0.00750 x 3.91 x [tex]10^{-1}[/tex] = 2.93 x [tex]10^{-3}[/tex] M

Therefore, the concentration of sodium formate in the buffer solution is 2.93 x [tex]10^{-3}[/tex] M.

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Answer:

a 87

Explanation:

b 56    c766   d77655

In the amino acid (AA) sequence of collagen, every third position must be occupied by glycine. Collagen is a structural protein, and its unique structure is due to the regular occurrence of glycine at the third position of its amino acid sequence.

Glycine (Gly) must occupy every third place in the AA (amino acid) sequence of collagen. This is due to the fact that glycine is the smallest amino acid and enables the close packing of collagen molecules, which is required for the development of collagen's distinctive triple helix structure.

The other two sites can be filled by any of the remaining 18 amino acids, although proline and hydroxyproline are frequently found there because they help the triple helix structure become more stable by forming hydrogen bonds.

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The empirical formula for Hg₂(NO₃)₂ is B) Hg(NO₃)₂. The answer is A)

To determine the empirical formula of a compound, we need to find the simplest whole-number ratio of atoms in the compound.

In this case, we have two mercury atoms (Hg₂), and two nitrate ions (NO₃)₂. To simplify, we can divide each by two, giving us one Hg atom and one NO₃ ion.

The formula for nitrate is NO₃⁻, which means it has one nitrogen atom (N) and three oxygen atoms (O). So, one NO₃ ion contains one N atom and three O atoms.

Therefore, the empirical formula for Hg₂(NO₃)₂ is Hg(NO₃)₂, which represents one mercury atom and two nitrate ions, each containing one N atom and three O atoms.

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The best choice to prepare a buffer with a pH of 9.0 is option b. C5H5N, C5H5NHCl (pkb for C5H5N is 8.76).

To make a buffer solution we can,

1. First, we need to find the corresponding pKa values for the given compounds. We can do this using the formula pKa = 14 - pKb.
a. NH3, NH4Cl: pKa = 14 - 4.75 = 9.25
b. C5H5N, C5H5NHCl: pKa = 14 - 8.76 = 5.24
c. HNO2, NaNO2: pKa = 3.33 (already given)
d. HCHO2, NaCHO2: pKa = 3.74 (already given)

2. To find the best buffer for a pH of 9.0, we need to choose a compound with a pKa value close to the desired pH. The Henderson-Hasselbalch equation states that pH = pKa + log([A-]/[HA]), where [A-] and [HA] are the concentrations of the conjugate base and weak acid, respectively. A good buffer has a pKa value close to the desired pH so that the ratio of [A-] to [HA] can be adjusted to achieve the target pH.

3. Comparing the pKa values of the given compounds to the desired pH of 9.0, we see that option b, C5H5N, C5H5NHCl, has the pKa value closest to 9.0 (5.24). Therefore, this compound would be the best choice to prepare a buffer with a pH of 9.0.

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Water-double solutes (a solution with double the amount of solute dissolved in it) is more concentrated than water.

Water-double solutes (a solution with double the amount of solute dissolved in it) is more concentrated than water. This can have various effects depending on the nature of the solute and the purpose of the solution. For example, in medical contexts, a more concentrated solution may be used to increase the effectiveness of a medication, while in industrial applications, a more concentrated solution may be more efficient or cost-effective in a chemical process.

However, it is important to note that increasing the concentration of a solute can also have negative effects, such as increased toxicity or reduced solubility, which may impact the safety or stability of the solution.

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The resistivity of the best-performing PANI is 200 Ω∙cm.

Resistivity is a measure of the material's opposition to the flow of electrical current through while Conductivity is the opposite of resistivity and is a measure of how well a material conducts electricity.

To determine the resistivity of the best-performing PANI described in the passage, we will use the given maximum conductivity value. The passage states that the best-performing PANI has a maximum conductivity of 5.0 × 10-3 (Ω∙cm)-1.

Step 1: Recall that resistivity (ρ) is the inverse of conductivity (σ). So, ρ = 1 / σ.

Step 2: Substitute the given conductivity value into the formula: ρ = 1 / (5.0 × 10-3 (Ω∙cm)-1).

Step 3: Calculate the resistivity: ρ = 1 / (5.0 × 10-3) = 200 Ω∙cm.

The resistivity of the best-performing PANI described in the passage is 200 Ω∙cm.

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The formula for sulfurous acid is A) H2SO3.

Sulfurous acid is a weak acid that is formed when sulfur dioxide (SO2) dissolves in water. The sulfur dioxide reacts with water to form sulfurous acid, which can then ionize to produce hydrogen ions (H+) and sulfite ions (SO32-).

The balanced chemical equation for the formation of sulfurous acid is:

SO2 + H2O → H2SO3

As you can see from this equation, one molecule of sulfur dioxide reacts with one molecule of water to form one molecule of sulfurous acid.

The formula for sulfurous acid reflects the fact that there are two hydrogen ions (H+) and one sulfite ion (SO32-) in the molecule. Therefore, the formula is H2SO3, with the subscript 2 indicating that there are two hydrogen ions in the molecule.

So once again, you are correct that the formula for sulfurous acid is A) H2SO3.

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Answer: False

Explanation:

This statement is not entirely accurate. The endocrine system is a complex network of glands that secrete hormones into the bloodstream to regulate and control the activities of various tissues and organs in the body. Unlike the nervous system, which sends nerve impulses to specific cells or tissues to trigger a response, the endocrine system uses hormones to communicate with cells throughout the body.

Hormones are chemical messengers that travel through the bloodstream and bind to specific receptors on target cells, triggering a response. These responses can be slow and long-lasting, allowing the endocrine system to regulate many processes in the body, including growth and development, metabolism, reproductive functions, and stress responses.

The technician needs to measure 2.6 mL of the concentrated hydrochloric acid solution and then add enough water to make a final volume of 250 mL to prepare a 0.125 M solution of hydrochloric acid.

To prepare a 0.125 M solution of hydrochloric acid (HCl) using a 12.0 M stock solution, the chemistry technician will need to dilute the concentrated solution. The dilution equation can be used to calculate the volume of the concentrated solution required:

C1V1 = C2V2

where C1 is the concentration of the concentrated solution, V1 is the volume of the concentrated solution, C2 is the desired concentration of the diluted solution (0.125 M), and V2 is the desired volume of the diluted solution (250 mL).

Substituting the given values into the equation, we get:
(12.0 M) V1 = (0.125 M) (250 mL)
Solving for V1, we get:
V1 = (0.125 M) (250 mL) / (12.0 M)
V1 = 2.60 mL (rounded to two decimal places)

Therefore, the chemistry technician will need to measure out 2.60 mL of the 12.0 M hydrochloric acid solution and add it to a volumetric flask. The flask should then be filled with distilled water up to the 250 mL mark, and the solution should be mixed well to ensure uniformity.

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