Be sure to answer all parts.

Find the pH during the titration of 20.00 mL of 0.1000 M triethylamine, (CH3CH2)3N (Kb = 5.2 × 10−4), with 0.1000 M HCl solution after the following additions of titrant.
20.20 mL:
pH =

Answers

Answer 1

a.

Initial moles of (CH₃CH₂)₃N = (0.1000 mol/L) × (20.00/1000 L) = 0.002 mol

Moles of HCl added = (0.1000 mol/L) × (13.00/1000 L) = 0.0013 mol

Addition of 1 mole of HCl reacts with 1 mole of (CH₃CH₂)₃N to 1 mole of (CH₃CH₂)₃NH⁺.

After addition of 13.00 mL of HCl:

Moles of (CH₃CH₂)₃N left unreacted = (0.002 - 0.0013) mol = 0.0007 mol

Moles of (CH₃CH₂)₃NH⁺ produced = 0.0013 mol

Hence, [(CH₃CH₂)₃NH⁺]/[(CH₃CH₂)₃N] = 0.0013/0.0007 = 13/7

Consider the dissociation of (CH₃CH₂)₃N:

(CH₃CH₂)₃N(aq) + H₂O(l) ⇌ (CH₃CH₂)₃NH⁺(aq) + OH⁻(aq) …… Kb = 5.2 × 10⁻⁴

Henderson-Hasselbalch equation:

pOH = pKb + log([(CH₃CH₂)₃NH⁺]/[(CH₃CH₂)₃N])

pOH = -log(5.2 × 10⁻⁴) + log(13/7) = 3.55

pH = pKw - pOH = 14.00 - 3.55 = 10.45

====

b.

Initial moles of (CH₃CH₂)₃N = 0.002 mol

Moles of HCl added = (0.1000 mol/L) × (20.80/1000 L) = 0.00208 mol

HCl is in excess.

Moles of HCl left unreacted = (0.00208 - 0.002) mol = 0.00008 mol

Volume of the final solution = (20.00 + 20.80) mL = 40.8 mL = 0.0408 L

In the final solution:

[H₃O⁺] = [HCl] = (0.00008 mol) / (0.0408 L) = 0.00196

pH = -log[H₃O⁺] = -log(0.00196) = 2.71

 

====

c.

Initial moles of (CH₃CH₂)₃N = 0.002 mol

Moles of HCl added = (0.1000 mol/L) × (29.00/1000 L) = 0.0029 mol

HCl is in excess.

Moles of HCl left unreacted = (0.0029 - 0.002) mol = 0.0009 mol

Volume of the final solution = (20.00 + 29.00) mL = 49 mL = 0.049 L

In the final solution:

[H₃O⁺] = [HCl] = (0.0009 mol) / (0.049 L) = 0.0184

pH = -log[H₃O⁺] = -log(0.0184) = 1.74


Related Questions

. How many grams of lithium are formed from the reaction if you begin with 89.5
grams of copper?
Cu
+
Li2S --> 2 Li +
CUS

Answers

Answer:

179g

Explanation:

Molar ratio for Copper : Lithium is

1:2

If there are 89.5g of copper

Grams for Lithium= 89.5 × 2 = 179g of Lithium

The amount of lithium are formed from the reaction if you begin with 89.5 grams of copper is 19.6 grams.

How do we convert mass into moles?

Mass can be converted into moles by using the below equation as:

n = W/M, where

W = given mass

M = molar mass

Moles of 89.5g of copper = 89.5g / 63.5g/mol = 1.4 mol

Given chemical reaction is:

Cu + Li₂S → 2Li + CuS

From the stoichiometry of the reaction, it is clear that

1.4 mole of Cu = produces 1.4 mole of CuS

1.4 mole of CuS = produced by 1.4 mole of Li₂S

1.4 mole of Li₂S = produces 2×1.4=2.8 moles of Li

Mass of 2.8 moles of Li = (2.8mol)(7g/mol) = 19.6g

Hence resultant mass of lithium is 19.6g.

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Given a volume of 47.8 mL of gas at STP, _______________ moles of O2 exist

Answers

At STP, a mole of any gas occupies 22.4 L. So given 48.7 mL—or 0.0487 L—of O2 gas at STP, the number of moles of O2 that exist is 0.00217 moles.

A cork cell was first observed by Robert Hooke in the year:
O 1556
O 1065
O 1965
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Answers

Answer:

1665

Explanation:

In 1665, Robert Hooke was the first to observe cork cells and their characteristic hexagonal shape, using the first optical microscope, which was invented by him at that time.

Which statement describes a physical property of copper?

Answers

Answer:

Copper is typically a solid and has a coppery, bronzy color. It is a metal and has a relatively high melting point. It has a strong luster and can conduct electricity.

Answer:

RESHAPE BY A FORCE.

Explanation:

1. It can be reshaped by a force. Physical property can be observed and measured without any changes in molecular composition.

2. A physical property is one that can be change without altering the identity of the substance. These set of properties is not concentration dependent they are use to describe matter. Example are: density, solubility, melting point and color and odor. For this case the second option seems to fit the description it can be reshape by force.

Knives should be stored in cluttered drawers.
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Answers

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Amir observes Wave 1 and Wave 2 crashing into each other at two different intervals. His experiments produce Wave 3 and Wave 4. Amir records his data in a table.

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What is the best statement about the data collected in Amir’s table?

Wave 3 resulted from destructive interference, and Wave 4 resulted from constructive interference.
Waves 3 and 4 resulted from constructive interference.
Waves 3 and 4 resulted from destructive interference.
Wave 3 resulted from constructive interference, and Wave 4 resulted from destructive interference.

Answers

Answer:

d

Explanation:

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Answer:

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Explanation:

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Answers

Answer:

MgBr2

Explanation:

(Mg^2+) + (Br^1-)

For every Mg we need 2 Br to balance out the compound.

Since magnesium has two outer electrons, it can donate one electron each to two bromine atoms having seven outer electrons in order for each of the atoms to have a complete octet.

Since the octet rule states that a stable atom must have eight electrons in its outermost shell, it follows that magnesium could give out two of its outermost electrons to two bromine atoms.

When that happens, each bromine atom which previously had seven electrons now have eight electrons, satisfying the octet rule. The correct formula of the compound is MgBr2.

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Answers

Answer:

0.525 M

Explanation:

As the problem deals with a dilution process, we can use the following formula:

C₁V₁=C₂V₂

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C₁ = 3.0 MV₁ = 35 mLC₂ = ?V₂ = 200 mL

We input the data given by the problem:

3.0 M * 35 mL = C₂ * 200 mL

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C₂ = 0.525 M

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Answer:

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Explanation:

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Answers

Answer:

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Explanation:

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Answers

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Answer:

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Answers

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Answer:

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Answers

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Answers

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Answer:

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2) Use In The Industrial Sector. The industrial sector makes similar use of natural gas liquids as a fuel for process heating and raw material to produce chemicals, fertilizers, and hydrogen.

3) Transportation.

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*

Answers

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Explanation:

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Explain in detail how low density polyethylene is made​

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Answer:

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Explanation:

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