a flask contains four gases: ch4, o2, c2h5, and n2. when the stopper is removed, which gas will diffuse the fastest?

The pI or isoelectric point of an Amino acid is the pH at which the net charge of the molecule is zero. For neutral amino acids, which have no charge, the pI can be calculated using the average of the two [tex]pK_a[/tex] values of its ionizable groups.

The two ionizable groups in neutral amino acids are the alpha-carboxyl group (-COOH) and the alpha-amino group (-[tex]NH_2[/tex]).

The [tex]pK_a[/tex] of the alpha-carboxyl group is around 2.2, while the [tex]pK_a[/tex] of the alpha-amino group is around 9.4.\

To calculate the pI, we take the average of these two pKa values:

pI = ([tex]pK_a1[/tex] + [tex]pK_a2[/tex]) / 2
pI = (2.2 + 9.4) / 2
pI = 5.8

Therefore, the pI of neutral amino acids is around 5.8.

This value can vary slightly depending on the specific amino acid and the conditions in which it is measured, but the calculation remains the same. The pI is an important parameter in protein biochemistry because it affects the solubility, stability, and behavior of proteins in different environments.

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The amount of energy involved in the combustion of 13.0 g of methane is 173 kcal. The answer is c.

The given chemical equation for the combustion of methane indicates that one mole of CH₄ reacts with two moles of O₂ to form one mole of CO₂ and two moles of H₂O. The enthalpy change (ΔH) for this reaction is -213 kcal.

To calculate the energy involved in the combustion of 13.0 g of methane, we first need to determine the number of moles of CH₄ involved in the reaction:

n(CH₄) = m/M

where m is the mass of CH₄ and M is the molar mass of CH₄.

The molar mass of CH₄ is 12.01 + 4(1.01) = 16.05 g/mol.

So, n(CH₄) = 13.0 g / 16.05 g/mol = 0.810 mol

Now, we can use the stoichiometry of the chemical equation to calculate the amount of energy involved in the combustion of 0.810 mol of CH₄:

ΔH = -213 kcal/mol

Energy = n(CH₄) × ΔH

Energy = 0.810 mol × (-213 kcal/mol)

Energy = -172.8 kcal

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Answer:

b. Helium.

The most abundant element in the Sun, by far, is hydrogen, which makes up about 74% of its mass. The second most abundant element is helium, which makes up about 24% of the Sun's mass. Oxygen, on the other hand, is much less abundant in the Sun, making up only about 0.1% of its mass.

Oxidation-reduction reactions, also known as redox reactions, are concerned about the concentration of electrons. In a redox reaction, one substance loses electrons (oxidation) while another substance gains electrons (reduction).

Oxidation-reduction (redox) reactions are chemical reactions that involve the transfer of electrons between species. In redox reactions, one species loses electrons (undergoes oxidation) while another species gains electrons (undergoes reduction). These reactions involve the transfer of electrons between two species, which ultimately affects the concentration of electrons in the system.

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The correct options that describe sp hybrid orbitals are:- The combination of one s and one p orbital results in the formation of one sp hybrid orbital, - The energy of an sp hybrid orbital lies between the energies of the original s and p orbitals that were mixed. and - Each sp hybrid orbital has one large and one small lobe.

An sp-hybridized atom has one unhybridized p orbital in its valence shell. The angle between two sp hybrid orbitals is 180° (not 90°). The combination of one s and one p orbital results in the formation of two sp hybrid orbitals. The energy of an sp hybrid orbital lies between the energies of the original s and p orbitals that were mixed. Each sp hybrid orbital has one large and one small lobe.

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Each unit of sodium borohydride (NaBH4) contains 4 reducing equivalents, so the answer is d. 4.

What is Reduction?

Reduction is a chemical reaction that involves the gain of one or more electrons by an atom, molecule, or ion. It is the opposite of oxidation, which involves the loss of electrons. Reduction reactions often involve the transfer of hydrogen atoms or the addition of electrons and typically result in a decrease in oxidation state.

Reducing equivalents refer to the number of electrons that are transferred during a redox reaction. In the case of sodium borohydride (NaBH4), there are 4 reducing equivalents because each molecule of NaBH4 can donate up to 4 electrons during a reduction reaction.

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Rehardens the newly arranged disulfide bonds as well as neutralizes any remaining waving lotion in the hair through oxidation is called a neutralizer.

Waving Lotion / Solution is the one that softens and swells the cuticle layer then it breaks the disulfide bonds through the process of reduction.

Neutralizer is the substance that  rehardens the newly arranged disulfide bonds as well as neutralizes any remaining waving lotion in the hair through oxidation.

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proline and glycine are frequently encountered in reverse turn due to their steric (spatial) properties that facilitate the change in direction of the polypeptide chain. When a polypeptide chain changes direction, it creates a reverse turn or a loop structure.

This change in direction is facilitated by the presence of certain amino acid residues, such as proline and glycine, which are commonly found in reverse turns. These residues are small and have unique structural characteristics that allow them to fit into the tight space created by the change in direction.

Proline, in particular, has a cyclic structure that restricts its flexibility and makes it ideal for forming a kink in the polypeptide chain.

Glycine, on the other hand, has a small side chain that enables it to occupy less space in the turn. Together, these amino acid residues enable the polypeptide chain to undergo the necessary spatial rearrangements required for protein folding and function.

What type of amino acid residues are commonly found in reverse turns of polypeptide chains?

A. Aromatic residues

B. Hydrophobic residues

C. Proline residues

D. Positively charged residues

Correct option: C. Proline residues.

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The isoelectric point of an amino acid with an acidic side chain is calculated by averaging the pKa values for the carboxyl group and the amino group.

At the isoelectric point, the amino acid has a neutral charge because it exists as a zwitterion, with a negatively charged carboxyl group and a positively charged amino group balancing each other out. If the pH is lower than the isoelectric point, the amino acid will have a net positive charge due to the protonation of the amino group, and if the pH is higher than the isoelectric point, the amino acid will have a net negative charge due to the deprotonation of the carboxyl group.

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Answer:

a. Molarity = number of moles / volume = 0.0294 mol / 0.250 L = 0.1176M

b. moles = 0.1174 mol/L x 0.0300 L

moles = 0.00352 moles

c. C2 = M1 x (0.030 L x 8) / 0.240 L

C2 = M1

The Flames have the three zones first outermost zone which has light blue in color, second  is yellow in the color and the third one is black in the color.

The Flame which is the visible gaseous part of the fire. The flame of the color that will depends on the temperature, the types of the fuel used and the  completeness of the combustion. It consist of different zones.

The outermost part of the flame, is the light blue in color. The middle layer, will consists of the part of the flame which is mostly yellowish to the orange in the color.  The last and the least hot region is mostly black in the color.

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The purpose of the wet paper towel in the Diels-Alder lab procedure is To encourage condensation during the reflux, preventing the reaction mixture from becoming too concentrated and potentially leading to the formation of unwanted side products option (B)

The purpose of the wet paper towel in the Diels-Alder lab procedure is to prevent the loss of solvent due to evaporation during the reflux process. The wet paper towel is placed on top of the round-bottom flask and acts as a cooling jacket.

As the solvent evaporates from the solution and condenses on the cool surface of the paper towel, it drips back down into the flask, preventing the solution from drying out. This helps maintain a constant volume and concentration of the reactants and ensures that the reaction proceeds as expected

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The pH of the solution is approximately 1.093.

To solve this problem, we need to use the equation for the neutralization of an acid and a base:

acid + base → salt + water

In this case, the acid is HCl and the base is NaOH, so the balanced equation is:

HCl + NaOH → NaCl + H2O

According to the equation, 1 mole of HCl reacts with 1 mole of NaOH to produce 1 mole of NaCl and 1 mole of water. We can use this fact to determine how much of each reactant is used up in the reaction.

First, we need to calculate the number of moles of HCl and NaOH in the solution:

moles of HCl = concentration × volume = 0.249 M × 0.0407 L = 0.01015 moles

moles of NaOH = concentration × volume = 0.108 M × 0.0364 L = 0.00394 moles

Next, we need to determine which reactant is limiting. The limiting reactant is the one that is completely used up in the reaction, and determines how much product can be formed. To do this, we compare the number of moles of each reactant:

HCl:NaOH = 0.01015:0.00394 = 2.58:1

Since the ratio is greater than 1:1, we can see that HCl is in excess and NaOH is limiting.

Therefore, all the NaOH will react with the HCl to form NaCl and water:

NaOH + HCl → NaCl + H2O

The number of moles of NaOH used up is equal to the number of moles of HCl that reacts:

moles of NaOH used up = 0.00394 moles

The remaining moles of HCl that did not react is:

moles of HCl remaining = 0.01015 - 0.00394 = 0.00621 moles

To calculate the concentration of the NaCl solution formed, we divide the number of moles of NaCl by the total volume of the solution:

total volume = 40.7 mL + 36.4 mL = 77.1 mL = 0.0771 L

moles of NaCl = moles of NaOH used up = 0.00394 moles

concentration of NaCl = moles of NaCl / total volume = 0.00394 moles / 0.0771 L = 0.0511 M

Finally, we can calculate the pH of the solution using the formula:

pH = -log[H+]

Since NaCl is a salt of a strong acid (HCl) and a strong base (NaOH), it will not contribute to the pH of the solution. Therefore, the pH is determined by the excess H+ ions from the HCl. To calculate the concentration of H+ ions in the solution, we can use the following formula:

[H+] = moles of HCl remaining / total volume

[H+] = 0.00621 moles / 0.0771 L = 0.0804 M

pH = -log[H+] = -log(0.0804) = 1.093

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The resulting width of the strip is approximately 4.875 cm, and the percent volume change after deformation is approximately 1.71875%.

We can use Poisson's ratio to calculate the change in width, and the formula for percent volume change to calculate the change in volume:

Poisson's ratio (ν) relates the lateral strain (εl) to the axial strain (εa) in a material:

ν = -εl / εa

For an isotropic material, ν is constant and equal to one-third of the ratio of the transverse (lateral) and axial elastic moduli:

ν = E_l / 2G

where E_l is the transverse (lateral) elastic modulus and G is the shear modulus.

For polystyrene, the lateral elastic modulus is approximately equal to the axial elastic modulus, so we can use:

ν ≈ 0.5

Given that the length of the strip changes from 10 cm to 10.5 cm, the axial strain is:

εa = (ΔL / L) = (10.5 cm - 10 cm) / 10 cm = 0.05

Using Poisson's ratio, we can calculate the lateral strain:

εl = -ν εa = -0.5 x 0.05 = -0.025

The resulting width of the strip is:

W' = W (1 + εl) = 5 cm (1 - 0.025) = 4.875 cm

The percent volume change is given by:

% volume change = (ΔV / V) x 100%

where ΔV is the change in volume and V is the original volume.The original volume of the strip is:

V = L x W x H = 10 cm x 5 cm x 2 cm = 100 cm^3

The final volume of the strip is:

V' = L' x W' x H' = 10.5 cm x 4.875 cm x 2 cm = 101.71875 cm^3

Therefore, the change in volume is:

ΔV = V' - V = 1.71875 cm^3

And the percent volume change is:

% volume change = (ΔV / V) x 100% = (1.71875 cm^3 / 100 cm^3) x 100% = 1.71875%.

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When the concentration of F- exceeds option C- 1.3 × 10⁻²M BaF₂ will precipitate.

The balanced chemical equation for the reaction between NaF and Ba²⁺ is:

Ba²⁺ + 2F⁻ → BaF₂(s)

The solubility product expression for BaF₂ is:

Ksp = [Ba²⁺][F⁻]²

At equilibrium, the ion product (Qsp) is equal to the Ksp. Since the solution initially contains 0.0099 M Ba²⁺, the ion product is:

Qsp = [Ba²⁺][F⁻]² = (0.0099)(0)² = 0

Since Qsp is less than the Ksp, no precipitation occurs. Now, let x be the concentration of F⁻ added from the NaF solution, then the concentration of F⁻ in solution is [F⁻] = 2x, and the ion product becomes:

Qsp = [Ba²⁺][F⁻]² = (0.0099)(2x)² = 0.0396x²

When Qsp = Ksp, the concentration of F⁻ is:

Ksp = Qsp = 0.0396x²

x = (Ksp/0.0396) = (1.7 x 10⁻⁶/0.0396) = 1.3 × 10⁻² M

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Since the pH is greater than 7, the solution is basic. So, the window-cleaning solution has a pH of 8.28, and the solution with a pOH of 3.00 has a pH of 11.00, which is basic.

To find the pH of a window-cleaning solution with a [H+] = 5.3 × 10^−9 M, we can use the formula:

pH = -log[H+]

First, we need to find the pH of the solution:

pH = -log(5.3 × 10^−9)
pH ≈ 8.28

Next, we'll determine the pH of a solution with a pOH of 3.00. We can use the following relationship:

pH + pOH = 14

Now, we can find the pH:

pH = 14 - pOH
pH = 14 - 3.00
pH = 11.00

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The change in potential energy, ΔU=Uf−Ui, of an alpha particle depends on the specific situation in which the particle is located.

In general, potential energy is defined as the energy stored within a system due to the position or configuration of its parts. For example, if an alpha particle is located at a point with a higher electrical potential than its initial position, it will have gained potential energy, resulting in a positive change in potential energy, ΔU>0. Conversely, if the alpha particle is located at a point with a lower electrical potential, it will have lost potential energy, resulting in a negative change in potential energy, ΔU<0. To determine the exact value of ΔU, the specific potential energy values at the initial and final positions of the alpha particle must be known.

To provide a specific value, you would need more information about the alpha particle's initial and final positions or the potential energy at these positions. However, keep in mind that the change in potential energy is the difference between the final and initial potential energies of the alpha particle.

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Answer:

Hydroxide and thio relaxers are not compatible because they work on different mechanisms to straighten hair. Hydroxide relaxers work by breaking the disulfide bonds in the hair, while thio relaxers work by breaking the protein bonds. Mixing these two types of relaxers could cause severe damage to the hair and scalp, leading to breakage, hair loss, and other issues. It is important to choose one type of relaxer and stick with it to achieve the desired results safely.

Explanation:

The mass of 9.86 × 10²⁴ molecules of CO₂ is approximately 720 g (option C).

To calculate the mass of 9.86 × 10²⁴ molecules of CO₂, we first need to determine the number of moles of CO₂ present in the given quantity.

Number of moles of CO₂ = (9.86 × 10²⁴ molecules) / Avogadro's number

Avogadro's number = 6.022 × 10²³ molecules/mol

Number of moles of CO₂ = (9.86 × 10²⁴ / (6.022 × 10²³) = 16.35 mol

Next, we can use the molar mass of CO₂ to calculate the mass of 16.35 moles of CO₂.

Mass of CO₂ = Number of moles of CO₂ × Molar mass of CO₂
Mass of CO₂ = 16.35 mol × 44.01 g/mol = 719.63 g

Therefore, by calculating we can say that the mass of 9.86 × 10²⁴ molecules of CO₂ is approximately 720 g (option C).

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Molecular structure of 1-pentyne has triple bond between carbon atoms 2 and 3, and the other carbon atoms and hydrogen atoms arranged in a linear chain.

To draw the molecular structure of 1-pentyne, follow these steps:

Draw a straight chain of five carbon atoms in a row, and label them 1 through 5 from left to right.

Place a triple bond (≡) between the second and third carbon atoms, which means that there are two more bonds that need to be added to each of these atoms.

Add a single bond to each of the other carbon atoms to fulfill their bonding requirements. This means that each carbon atom should have a total of four bonds.

Add hydrogen atoms to each carbon atom to complete their bonding requirements. Carbon atoms 1, 4 and 5 should each have three hydrogen atoms attached, while carbon atoms 2 and 3 should each have one hydrogen atom attached.

The resulting structure should look like this:

H    H    H    H    H

 |    |    |    |    |

H--C--C≡C -- C--C --H

| |

H H

This represents the molecular structure of 1-pentyne, with the triple bond between carbon atoms 2 and 3, and the other carbon atoms and hydrogen atoms arranged in a linear chain.

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The TLC analysis of 2-bromooctane and 2-decene, silica gel would be the adsorbent of choice due to its lower polarity and ability to effectively adsorb nonpolar compounds.

The choice of adsorbent for thin-layer chromatography (TLC) analysis depends on the polarity of the compound being analyzed. Alumina and silica gel are two commonly used adsorbents in TLC, with alumina being more polar than silica gel.

2-bromooctane and 2-decene are both nonpolar compounds, which means they will tend to have stronger interactions with less polar adsorbents. Therefore, silica gel would be a better choice for their TLC analysis.

Silica gel has a lower polarity than alumina and is often used for the separation of nonpolar and slightly polar compounds. It is a highly porous material that can adsorb small molecules effectively, making it a great choice for TLC.

In contrast, alumina is a more polar adsorbent and is typically used for the separation of polar compounds. It is also a good choice for acidic and basic compounds, but not for nonpolar compounds such as 2-bromooctane and 2-decene.

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So, we need to add 24.07 grams of dry [tex]NH_4Cl[/tex] to 2.40 L of the 0.800 M ammonia solution to prepare a buffer solution with a pH of 8.90.

To prepare a buffer solution with pH 8.90, we need to use the Henderson-Hasselbalch equation, pH = pKa + log([A-]/[HA]).

First, we need to find the pKa of ammonia using the Kb value:

Kb = [[tex]NH_4Cl[/tex]+][OH-]/[NH3]

1.77 x 10^-5 = [tex]x^2[/tex] / (0.8 - x)

here x = [OH-] = [[tex]NH_4Cl[/tex]+].

Thus, [NH3] = 0.8 - x = 0.8 - 0.00133 = 0.79867 M.

pKa = -log(Ka) = 9.24.

Next, we can plug in the given pH and pKa values into the Henderson-Hasselbalch equation:

8.90 = 9.24 + log([A-]/[HA])

log([A-]/[HA]) = -0.34

[A-]/[HA] = 0.45

Finally, we can set up an ICE table to find the amount of [tex]NH_4Cl[/tex] needed:

[tex]NH_4Cl[/tex](s) → [tex]NH_4Cl[/tex]+(aq) + Cl-(aq)

I:    n/a           0 M         0 M

C:   -x           +x M       +x M

E:  -x           0.45x M   0.55x M

where x is the amount of [tex]NH_4Cl[/tex] needed to create 0.45 M of NH4+ in solution.

From the equation, we know that 1 mole of [tex]NH_4Cl[/tex] produces 1 mole of NH4+.

Thus, 0.45 moles of NH+ requires 0.45 moles of [tex]NH_4Cl[/tex].

The molar mass of [tex]NH_4Cl[/tex] is 53.49 g/mol.

Therefore, the mass of [tex]NH_4Cl[/tex] needed is:

mass = 0.45 mol x 53.49 g/mol = 24.07 g.

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The hydrocarbon in the given options is option D) CH3CH2CH2CH3, which is also known as butane.

A hydrocarbon is a compound consisting of only hydrogen and carbon atoms. In this case, option D (CH3CH2CH2CH3) represents a hydrocarbon, which is specifically butane, an alkane with four carbon atoms. The other options contain elements other than hydrogen and carbon, such as sulfur (S), oxygen (O), and nitrogen (N), which disqualify them as hydrocarbons.

Butane is a hydrocarbon. It is specifically a saturated hydrocarbon which has the molecular formula C4H10. It is an alkane with a straight-chain structure consisting of four carbon atoms bonded to each other and with ten hydrogen atoms attached to them.

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In both cases, the platinum components provide an efficient and stable medium for the respective redox reactions to occur, ensuring that the electron transfer process is smooth and effective.

To know about the role of a platinum disc and platinum wire in the following half-cell reactions:

1. A disc of platinum used for: Pt2+ (aq) + 2e- → Pt (s)
2. Platinum wire used for: 2Cl- (aq) → Cl2 (g) + 2e-

In these reactions, the platinum disc and platinum wire act as inert electrodes, providing a surface for the redox reactions to take place.

For the first reaction, the platinum disc serves as a solid surface for the reduction of Pt2+ ions to solid platinum (Pt). This occurs when Pt2+ ions gain 2 electrons (2e-) to form Pt (s).

For the second reaction, the platinum wire acts as an electrode for the oxidation of Cl- ions. Here, 2 Cl- ions lose 2 electrons (2e-) to form Cl2 gas.

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Of the following, a 0.1 M aqueous solution of sucrose will have the highest freezing point.
 Based on your question, the correct answer is:

"Of the following, a 0.1 M aqueous solution of __e. sucrose__ will have the highest freezing point."

This is because sucrose is a non-electrolyte and does not dissociate into ions in an aqueous solution, leading to a smaller change in the freezing point compared to the other ionic compounds listed.

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The atomic number (Z) of Iminium (Im) is 125, and since alpha decay results in the loss of 2 protons, Z will decrease by 2, giving a value of 123 for the newly formed element.

After a decay event by alpha decay, the Iminium (Im) atom with atomic number 125 (Z) and atomic mass number 282 (A) will change. Alpha decay involves the loss of 2 protons and 2 neutrons from the nucleus. Therefore, the new values for A and Z will be:

- New atomic number (Z) = 125 - 2 = 123
- New atomic mass number (A) = 282 - 4 = 278

So, the atom that was formerly 282Im will now have an atomic number (Z) of 123 and an atomic mass number (A) of 278.

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While hydrogen peroxide is an oxidizing agent and has the chemical formula, water is a polar molecule. If hydrogen peroxide is utilized as an oxidizing agent, water can behave as a polar solvent. Comparatively speaking to water, hydrogen peroxide's bonds are weak.

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A high RF value results from a compound strongly binding to the polar silica gel stationary phase on a TLC plate.

Polar compounds are more strongly attracted to the polar silica gel stationary phase than non-polar compounds, so they travel more slowly along the plate and have a higher RF value. Polar compounds also have a greater difference in polarity between the mobile and stationary phases, so they move more slowly and require more strongly polar solvents to elute them.

A low RF value results when a compound binds weakly to the stationary phase and is eluted more quickly.

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The mass percent of H in the sodium bicarbonate, NaHCO₃ is 1.20 %. The correct option is A.

The molar mass of the sodium bicarbonate, NaHCO₃  is as :

The Molar mass of NaHCO₃ = 1(Na) + 1(H) + 1(C) + 3(O)

The Molar mass of NaHCO₃ = 23.00 + 1.01 + 12.01 + (3 x 16.00)

The Molar mass of  NaHCO₃ = 84.01 g/mol

The mass percent H, in NaHCO₃ = (mass of H / mass of NaHCO3) x 100%

The mass percent H, in NaHCO₃ = (1.01 g / 84.01 g) x 100%

The mass percent H, in NaHCO₃ = 1.20%

The mass percent of the hydrogen, in the NaHCO₃ 1.20%. Therefore, the option A is correct.

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The cluster bomb unit (CBU) that consists of a SUU-65/B dispenser and a submunitions payload of kinetic energy penetrators (KEP) is the CBU-97.

The CBU that consists of a SUU-65/B dispenser and a submunitions payload of kinetic energy penetrators (KEP) is the CBU-97 Sensor Fuzed Weapon (SFW). The CBU-97 SFW is designed to effectively target and destroy a variety of enemy assets, such as armored vehicles and other ground targets, using its advanced sensor technology and KEP submunitions.

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